Definition of reflection and transmission operators
Denote the cosine of the angle that a right circular cone makes with the normal
by
(Figure 3.1A). Furthermore let the incident radiance, which is a function of
incident angle ,
be denoted by
where the plus sign indicates the
downward direction. The total radiance transmitted through the slab at a particular
cosine angle
is given by [60]
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(3.1) |
The total radiance reflected by the sample is
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(3.2) |
Figure:
Geometric description of nomenclature. Figure A illustrates the
incident radiance
with the cosine of the angle of incidence
equal to .
Figure B shows the nomenclature for the upward and downward
radiances from each surface of the slab.
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The operators
and
may be written in matrix form
 |
(3.3) |
where the angles
and
are chosen according to the particular quadrature scheme
desired. The superscripts ij indicate the entry ij in the matrices T and R. The
radiances
and
correspondingly may be written as vectors
 |
(3.4) |
The matrix star multiplication
is defined to directly correspond to an
integration similar to those in Equations (3.1) and (3.2)
 |
(3.5) |
then
 |
(3.6) |
where
is the jth quadrature angle and wj is its corresponding weight.
The identity matrix E is then
 |
(3.7) |
where
is the usual Kronecker delta. Grant and Hunt have shown that this algebra
is a semi-group [21,22] and have proven that all matrix manipulations in
Section 3.2
are valid mathematically. It is sometimes useful to consider these matrix ``star
multiplications'' as normal matrix multiplications which include a diagonal matrix c
 |
(3.8) |
Thus a matrix star multiplication may be written
 |
(3.9) |
where the multiplications on the R.H.S. of Equation (3.9) are usual matrix
multiplications.
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