# Optical absorption spectrum of Porphin in toluene # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by J. Li on 12-11-1997 using a Cary 3. # The absorption values were collected using a spectral bandwidth of 1.0 nm, a signal averaging time of 0.133 sec, a data interval of 0.25 nm, and a scan rate of 112.5 nm/min. # # These measurements were scaled to make the molar extinction coefficient match # the value of 261000 cm-1/M at 396.3 nm. These values were # then interpolated to report extinction coefficients at regular 1nm intervals # # The reported molar extinction coefficient is from # Eisner, U. and R. P. Linstead (1955) Chlorophyll and related compounds. Part II. The dehydrogenation of chlorin to porphin and the number of extra hydrogen atoms in the chlorins. J. Chem. Soc. 3749-3754. # ##Wavelength (nm) Molar Extinction (cm-1/M) 289.75 12059 290 10937 290.25 12215 290.5 12384 290.75 13201 291 13708 291.25 12188 291.5 12368 291.75 12414 292 12277 292.25 12681 292.5 11467 292.75 14363 293 11738 293.25 11433 293.5 12944 293.75 11525 294 11720 294.25 12695 294.5 13794 294.75 13494 295 13453 295.25 12499 295.5 12660 295.75 13065 296 12539 296.25 12525 296.5 13729 296.75 13117 297 12545 297.25 14064 297.5 13314 297.75 14001 298 12961 298.25 13194 298.5 13535 298.75 13260 299 13881 299.25 12949 299.5 12981 299.75 12837 300 12851 300.25 13841 300.5 13452 300.75 13186 301 12794 301.25 13751 301.5 13823 301.75 13385 302 12220 302.25 13493 302.5 14484 302.75 12343 303 12020 303.25 13106 303.5 12684 303.75 12380 304 13023 304.25 12215 304.5 13102 304.75 13268 305 12649 305.25 13638 305.5 13991 305.75 13465 306 11862 306.25 13507 306.5 11257 306.75 13914 307 12564 307.25 12127 307.5 13603 307.75 13218 308 12180 308.25 12696 308.5 12564 308.75 12592 309 13761 309.25 13128 309.5 12933 309.75 12726 310 12609 310.25 13608 310.5 12916 310.75 14155 311 12654 311.25 13290 311.5 12578 311.75 13161 312 11573 312.25 13273 312.5 14062 312.75 13883 313 12469 313.25 13019 313.5 11966 313.75 12186 314 14579 314.25 13288 314.5 12736 314.75 13907 315 14106 315.25 14371 315.5 12929 315.75 13217 316 13545 316.25 13473 316.5 13570 316.75 12407 317 14861 317.25 12624 317.5 15372 317.75 12463 318 14376 318.25 15912 318.5 13194 318.75 13978 319 14174 319.25 14007 319.5 14856 319.75 15841 320 15545 320.25 14036 320.5 15010 320.75 13987 321 14893 321.25 14479 321.5 14216 321.75 14826 322 15278 322.25 14992 322.5 14076 322.75 15191 323 15632 323.25 15494 323.5 14818 323.75 14154 324 15753 324.25 15180 324.5 14630 324.75 16371 325 16399 325.25 16020 325.5 15235 325.75 16413 326 15729 326.25 17073 326.5 17093 326.75 16719 327 16257 327.25 17217 327.5 17545 327.75 18730 328 16246 328.25 18211 328.5 18141 328.75 18010 329 17313 329.25 16742 329.5 17908 329.75 18947 330 19298 330.25 18684 330.5 20252 330.75 18126 331 20155 331.25 19869 331.5 20767 331.75 22423 332 22196 332.25 22337 332.5 21527 332.75 21652 333 22412 333.25 22525 333.5 21377 333.75 21700 334 22487 334.25 22206 334.5 22035 334.75 22585 335 24299 335.25 23209 335.5 22541 335.75 23970 336 25107 336.25 25159 336.5 23401 336.75 24942 337 23606 337.25 24971 337.5 24586 337.75 24777 338 24834 338.25 25690 338.5 26162 338.75 24724 339 25346 339.25 25163 339.5 26556 339.75 26820 340 26196 340.25 25071 340.5 25984 340.75 24206 341 25775 341.25 26802 341.5 25854 341.75 25313 342 26331 342.25 25529 342.5 25496 342.75 26786 343 26637 343.25 28951 343.5 25283 343.75 27906 344 27484 344.25 27037 344.5 26854 344.75 26884 345 27482 345.25 27878 345.5 27829 345.75 27438 346 27962 346.25 29324 346.5 29481 346.75 27686 347 30723 347.25 29246 347.5 30055 347.75 30154 348 29088 348.25 30555 348.5 30086 348.75 30767 349 29498 349.25 30644 349.5 29531 349.75 29793 350 29987 350.25 30944 350.5 30058 350.75 30739 351 32087 351.25 30698 351.5 31247 351.75 31759 352 32004 352.25 31524 352.5 32085 352.75 32115 353 32081 353.25 32059 353.5 32481 353.75 32418 354 33169 354.25 34071 354.5 33144 354.75 32385 355 33271 355.25 32821 355.5 33525 355.75 33441 356 34517 356.25 33469 356.5 33901 356.75 34485 357 32819 357.25 33491 357.5 33816 357.75 33521 358 34160 358.25 34165 358.5 34095 358.75 34421 359 34282 359.25 33586 359.5 33839 359.75 33306 360 34519 360.25 33511 360.5 33864 360.75 34320 361 34159 361.25 33739 361.5 34051 361.75 34309 362 34828 362.25 34171 362.5 34812 362.75 34749 363 35476 363.25 34385 363.5 35236 363.75 35254 364 35527 364.25 35608 364.5 36745 364.75 36330 365 36600 365.25 37828 365.5 36870 365.75 37016 366 37693 366.25 37921 366.5 39018 366.75 38335 367 39300 367.25 39721 367.5 40054 367.75 40973 368 41371 368.25 42049 368.5 42532 368.75 43367 369 43935 369.25 45546 369.5 45752 369.75 45419 370 46675 370.25 47397 370.5 48374 370.75 49546 371 49858 371.25 51926 371.5 51978 371.75 52994 372 54061 372.25 54905 372.5 55877 372.75 56205 373 57000 373.25 58131 373.5 59229 373.75 60327 374 61043 374.25 61960 374.5 64246 374.75 65859 375 66385 375.25 67753 375.5 69527 375.75 70109 376 71743 376.25 72996 376.5 73790 376.75 77031 377 78384 377.25 79534 377.5 80175 377.75 82483 378 83219 378.25 84039 378.5 86291 378.75 87782 379 89144 379.25 90598 379.5 91422 379.75 92914 380 93617 380.25 94403 380.5 96247 380.75 98878 381 99051 381.25 101057 381.5 103126 381.75 104782 382 106770 382.25 107052 382.5 109563 382.75 110411 383 112218 383.25 114131 383.5 116189 383.75 118284 384 119864 384.25 121405 384.5 124350 384.75 126925 385 128466 385.25 130735 385.5 133215 385.75 135885 386 139715 386.25 141616 386.5 144012 386.75 148128 387 149361 387.25 152860 387.5 155930 387.75 159504 388 161377 388.25 165439 388.5 169574 388.75 171891 389 175190 389.25 178639 389.5 181586 389.75 185238 390 189294 390.25 192376 390.5 196142 390.75 198589 391 202769 391.25 205853 391.5 209075 391.75 214167 392 216601 392.25 221206 392.5 225471 392.75 230143 393 233995 393.25 235821 393.5 241283 393.75 243843 394 246302 394.25 250632 394.5 252755 394.75 255992 395 258848 395.25 260009 395.5 260776 395.75 261054 396 259659 396.25 261243 396.5 260025 396.75 257915 397 255394 397.25 253574 397.5 251465 397.75 245374 398 242543 398.25 236434 398.5 230907 398.75 226389 399 219696 399.25 213510 399.5 207873 399.75 200874 400 193729 400.25 189535 400.5 181288 400.75 174291 401 168052 401.25 161882 401.5 154210 401.75 148846 402 142700 402.25 137060 402.5 130417 402.75 124614 403 120098 403.25 114149 403.5 109099 403.75 103440 404 98046 404.25 94201 404.5 89488 404.75 84989 405 81168 405.25 77128 405.5 73698 405.75 70243 406 65924 406.25 63521 406.5 60185 406.75 57053 407 53920 407.25 51090 407.5 48614 407.75 46402 408 44422 408.25 41690 408.5 39713 408.75 37590 409 35923 409.25 34230 409.5 32434 409.75 31212 410 29338 410.25 27871 410.5 26488 410.75 25213 411 24475 411.25 23211 411.5 21945 411.75 21481 412 20603 412.25 19555 412.5 18643 412.75 18772 413 17842 413.25 16862 413.5 16142 413.75 15868 414 15542 414.25 14406 414.5 13436 414.75 13422 415 12633 415.25 12163 415.5 11836 415.75 11064 416 10542 416.25 10178 416.5 9994 416.75 9909 417 9564 417.25 9117 417.5 8435 417.75 8188 418 7970 418.25 7540 418.5 7270 418.75 6712 419 6845 419.25 6770 419.5 6677 419.75 6690 420 6197 420.25 5881 420.5 5503 420.75 5248 421 5492 421.25 5220 421.5 4905 421.75 4760 422 4882 422.25 4459 422.5 3967 422.75 4244 423 4418 423.25 3956 423.5 4006 423.75 3849 424 3550 424.25 3523 424.5 3403 424.75 3438 425 2979 425.25 3153 425.5 2974 425.75 3083 426 3169 426.25 3092 426.5 2960 426.75 2711 427 2663 427.25 3093 427.5 2537 427.75 2621 428 2849 428.25 2845 428.5 2140 428.75 2409 429 2721 429.25 2830 429.5 1997 429.75 2417 430 1736 430.25 2482 430.5 2077 430.75 2096 431 2215 431.25 2232 431.5 2086 431.75 1941 432 2399 432.25 1915 432.5 2145 432.75 1931 433 2229 433.25 1937 433.5 2038 433.75 1806 434 1819 434.25 1563 434.5 1955 434.75 1786 435 1765 435.25 1872 435.5 1259 435.75 1612 436 1111 436.25 1284 436.5 1759 436.75 1970 437 1805 437.25 1070 437.5 1621 437.75 1511 438 1519 438.25 1140 438.5 1293 438.75 1656 439 1981 439.25 1559 439.5 1531 439.75 1949 440 1415 440.25 1284 440.5 1458 440.75 1872 441 1492 441.25 1233 441.5 1678 441.75 1242 442 1279 442.25 1036 442.5 1285 442.75 1460 443 1462 443.25 1462 443.5 1221 443.75 1601 444 1429 444.25 1310 444.5 1529 444.75 1486 445 1115 445.25 1768 445.5 1346 445.75 1458 446 1258 446.25 1121 446.5 1306 446.75 1314 447 1467 447.25 1655 447.5 1674 447.75 1471 448 1247 448.25 1588 448.5 1357 448.75 1098 449 1562 449.25 1365 449.5 983 449.75 1614 450 1743 450.25 1084 450.5 1207 450.75 1189 451 1347 451.25 1323 451.5 1268 451.75 1261 452 1270 452.25 1597 452.5 1435 452.75 1587 453 1282 453.25 1475 453.5 1473 453.75 1358 454 1768 454.25 1546 454.5 1367 454.75 1538 455 1475 455.25 1770 455.5 1552 455.75 1637 456 1404 456.25 1799 456.5 1994 456.75 1632 457 2079 457.25 1857 457.5 1675 457.75 1470 458 1670 458.25 1481 458.5 1552 458.75 2004 459 1995 459.25 1953 459.5 1636 459.75 1755 460 2228 460.25 1887 460.5 2431 460.75 2096 461 1961 461.25 2173 461.5 2165 461.75 2252 462 2043 462.25 2088 462.5 2273 462.75 2068 463 2040 463.25 2110 463.5 2021 463.75 2288 464 2029 464.25 2114 464.5 2484 464.75 1983 465 1998 465.25 2116 465.5 1938 465.75 2099 466 2275 466.25 2065 466.5 2054 466.75 2481 467 2120 467.25 2401 467.5 2298 467.75 2370 468 2306 468.25 2473 468.5 2526 468.75 2549 469 2337 469.25 2314 469.5 2733 469.75 2662 470 2729 470.25 2774 470.5 3048 470.75 3123 471 2858 471.25 2913 471.5 3404 471.75 3200 472 3279 472.25 3320 472.5 3191 472.75 3373 473 3472 473.25 3594 473.5 3279 473.75 3922 474 3637 474.25 3981 474.5 4479 474.75 4469 475 4935 475.25 5333 475.5 5717 475.75 5637 476 5916 476.25 6622 476.5 7451 476.75 7366 477 7904 477.25 8161 477.5 8471 477.75 8726 478 9011 478.25 9405 478.5 9986 478.75 10156 479 10060 479.25 10738 479.5 11133 479.75 10981 480 11300 480.25 11727 480.5 12095 480.75 11754 481 12449 481.25 12588 481.5 12800 481.75 12758 482 13167 482.25 13421 482.5 13436 482.75 13411 483 13763 483.25 14087 483.5 14009 483.75 14321 484 13919 484.25 14434 484.5 14725 484.75 14927 485 14863 485.25 15073 485.5 15418 485.75 15721 486 15669 486.25 16142 486.5 16433 486.75 16598 487 16778 487.25 17230 487.5 17234 487.75 17610 488 17944 488.25 17855 488.5 17920 488.75 18221 489 17771 489.25 18044 489.5 17864 489.75 18102 490 17770 490.25 17758 490.5 17582 490.75 17237 491 17771 491.25 17548 491.5 17001 491.75 16616 492 16721 492.25 16702 492.5 16261 492.75 16418 493 15962 493.25 15671 493.5 15127 493.75 15226 494 15161 494.25 15212 494.5 14379 494.75 14057 495 13686 495.25 13757 495.5 13281 495.75 13027 496 12439 496.25 12514 496.5 12234 496.75 11775 497 11375 497.25 11132 497.5 10611 497.75 10620 498 10235 498.25 9908 498.5 9743 498.75 9521 499 9215 499.25 8895 499.5 9089 499.75 8397 500 8243 500.25 7739 500.5 7709 500.75 7174 501 6968 501.25 7006 501.5 6588 501.75 6212 502 6263 502.25 5799 502.5 5945 502.75 5425 503 5216 503.25 5019 503.5 4999 503.75 4506 504 4644 504.25 4343 504.5 4557 504.75 4049 505 4174 505.25 3900 505.5 3932 505.75 3474 506 3536 506.25 3627 506.5 3413 506.75 3479 507 3447 507.25 3369 507.5 2827 507.75 3010 508 2788 508.25 3235 508.5 2527 508.75 2759 509 2883 509.25 2632 509.5 2587 509.75 2770 510 2438 510.25 2489 510.5 2452 510.75 2580 511 2178 511.25 2439 511.5 2278 511.75 2173 512 2120 512.25 2154 512.5 2158 512.75 1989 513 2076 513.25 1949 513.5 2329 513.75 2325 514 2217 514.25 2261 514.5 2199 514.75 2221 515 2296 515.25 2700 515.5 2340 515.75 2857 516 2454 516.25 2771 516.5 2709 516.75 2659 517 2864 517.25 3046 517.5 2704 517.75 3006 518 2540 518.25 2809 518.5 2653 518.75 3008 519 3157 519.25 3038 519.5 3206 519.75 3306 520 2763 520.25 2692 520.5 3113 520.75 2931 521 2442 521.25 2620 521.5 2677 521.75 2555 522 2395 522.25 2295 522.5 2313 522.75 2053 523 2091 523.25 2504 523.5 2262 523.75 2340 524 2180 524.25 2084 524.5 1823 524.75 2022 525 1894 525.25 2007 525.5 1846 525.75 1945 526 1967 526.25 1432 526.5 1959 526.75 1408 527 2036 527.25 1524 527.5 1504 527.75 1647 528 1444 528.25 1375 528.5 1456 528.75 1732 529 1741 529.25 1333 529.5 1050 529.75 1030 530 1558 530.25 1437 530.5 1730 530.75 1458 531 1257 531.25 1350 531.5 1133 531.75 1299 532 956 532.25 1022 532.5 1088 532.75 943 533 991 533.25 888 533.5 1118 533.75 876 534 877 534.25 1059 534.5 859 534.75 1170 535 1230 535.25 818 535.5 976 535.75 948 536 915 536.25 768 536.5 700 536.75 877 537 552 537.25 479 537.5 717 537.75 849 538 1195 538.25 501 538.5 508 538.75 644 539 377 539.25 679 539.5 909 539.75 673 540 659 540.25 582 540.5 646 540.75 595 541 709 541.25 846 541.5 718 541.75 860 542 694 542.25 666 542.5 670 542.75 970 543 956 543.25 563 543.5 784 543.75 1020 544 345 544.25 839 544.5 954 544.75 900 545 685 545.25 781 545.5 639 545.75 747 546 596 546.25 789 546.5 867 546.75 1153 547 881 547.25 1010 547.5 1113 547.75 1195 548 1202 548.25 1027 548.5 1033 548.75 969 549 885 549.25 990 549.5 957 549.75 1229 550 999 550.25 1143 550.5 1676 550.75 1756 551 1486 551.25 1460 551.5 1779 551.75 2047 552 1737 552.25 1861 552.5 1805 552.75 2009 553 2075 553.25 2109 553.5 2328 553.75 1966 554 2121 554.25 2234 554.5 2205 554.75 2210 555 2108 555.25 2101 555.5 2327 555.75 1980 556 2630 556.25 2288 556.5 2516 556.75 2234 557 2720 557.25 2689 557.5 2563 557.75 2812 558 3217 558.25 3351 558.5 3316 558.75 3688 559 3788 559.25 3962 559.5 4232 559.75 4589 560 4517 560.25 4901 560.5 4749 560.75 5011 561 5406 561.25 5357 561.5 5941 561.75 5694 562 5852 562.25 6035 562.5 5674 562.75 6186 563 5978 563.25 5836 563.5 5737 563.75 6123 564 5832 564.25 5570 564.5 5240 564.75 5461 565 5542 565.25 5140 565.5 4869 565.75 4868 566 4685 566.25 4569 566.5 4903 566.75 4696 567 5165 567.25 4473 567.5 4698 567.75 4865 568 4778 568.25 4832 568.5 4654 568.75 4783 569 4715 569.25 4997 569.5 4742 569.75 4744 570 4744 570.25 4810 570.5 4713 570.75 4825 571 4877 571.25 4963 571.5 4711 571.75 4513 572 4662 572.25 4554 572.5 4595 572.75 4678 573 4405 573.25 4203 573.5 4130 573.75 3881 574 4059 574.25 3606 574.5 3877 574.75 3591 575 3310 575.25 3321 575.5 3028 575.75 3109 576 2915 576.25 2818 576.5 2940 576.75 2845 577 2745 577.25 2731 577.5 2516 577.75 2368 578 2365 578.25 2291 578.5 2510 578.75 2150 579 2110 579.25 2183 579.5 2054 579.75 2037 580 2415 580.25 1676 580.5 1989 580.75 2069 581 1907 581.25 1819 581.5 1911 581.75 1662 582 1887 582.25 1661 582.5 1641 582.75 1416 583 1869 583.25 1560 583.5 1311 583.75 1319 584 1429 584.25 1483 584.5 1349 584.75 1028 585 1143 585.25 1219 585.5 1114 585.75 1245 586 1277 586.25 797 586.5 997 586.75 1070 587 1025 587.25 743 587.5 1170 587.75 1222 588 916 588.25 902 588.5 614 588.75 1013 589 1002 589.25 920 589.5 1066 589.75 1114 590 545 590.25 548 590.5 788 590.75 619 591 1059 591.25 1153 591.5 783 591.75 675 592 856 592.25 659 592.5 584 592.75 506 593 739 593.25 599 593.5 463 593.75 72 594 342 594.25 626 594.5 855 594.75 393 595 499 595.25 437 595.5 269 595.75 406 596 419 596.25 359 596.5 639 596.75 610 597 596 597.25 588 597.5 501 597.75 -107 598 480 598.25 632 598.5 186 598.75 790 599 444 599.25 556 599.5 559 599.75 444 600 138 600.25 189 600.5 329 600.75 208 601 206 601.25 621 601.5 748 601.75 326 602 413 602.25 377 602.5 296 602.75 585 603 593 603.25 428 603.5 371 603.75 465 604 632 604.25 182 604.5 282 604.75 567 605 401 605.25 365 605.5 574 605.75 446 606 357 606.25 558 606.5 983 606.75 470 607 679 607.25 541 607.5 443 607.75 515 608 567 608.25 986 608.5 655 608.75 530 609 402 609.25 456 609.5 361 609.75 447 610 487 610.25 543 610.5 766 610.75 554 611 567 611.25 816 611.5 709 611.75 613 612 1011 612.25 609 612.5 897 612.75 638 613 909 613.25 737 613.5 765 613.75 667 614 892 614.25 870 614.5 771 614.75 1001 615 1138 615.25 1158 615.5 831 615.75 1055 616 1301 616.25 646 616.5 1003 616.75 1247 617 1116 617.25 1013 617.5 550 617.75 806 618 1077 618.25 937 618.5 992 618.75 1094 619 506 619.25 1128 619.5 449 619.75 948 620 667 620.25 749 620.5 989 620.75 614 621 671 621.25 720 621.5 302 621.75 862 622 597 622.25 515 622.5 535 622.75 396 623 39 623.25 130 623.5 315 623.75 429 624 687 624.25 -174 624.5 535 624.75 147 625 -261 625.25 284 625.5 -93 625.75 -56 626 183 626.25 -373 626.5 294 626.75 63 627 -55 627.25 36 627.5 -140 627.75 0 628 151 628.25 201 628.5 294 628.75 313 629 331 629.25 -138 629.5 -203 629.75 -129 630 268 630.25 593 630.5 -64 630.75 -24 631 329 631.25 171 631.5 -235 631.75 -131 632 -51 632.25 174 632.5 -282 632.75 566 633 293 633.25 208 633.5 -76 633.75 -247 634 -122 634.25 424 634.5 -49 634.75 74 635 -32 635.25 401 635.5 565 635.75 34 636 170 636.25 -32 636.5 400 636.75 -260 637 -148 637.25 180 637.5 358 637.75 121 638 164 638.25 -229 638.5 667 638.75 25 639 -22 639.25 -50 639.5 -306 639.75 -75 640 -27 640.25 115 640.5 -12 640.75 94 641 -62 641.25 361 641.5 -287 641.75 95 642 80 642.25 55 642.5 -341 642.75 492 643 -45 643.25 -365 643.5 -298 643.75 -31 644 243 644.25 -157 644.5 -411 644.75 -318 645 120 645.25 -236 645.5 11 645.75 -338 646 -125 646.25 -31 646.5 106 646.75 -37 647 358 647.25 378 647.5 -202 647.75 -142 648 -78 648.25 -26 648.5 -16 648.75 111 649 317 649.25 42 649.5 -77 649.75 296 650 276 650.25 200 650.5 74 650.75 -115 651 110 651.25 -88 651.5 175 651.75 85 652 134 652.25 -125 652.5 -360 652.75 156 653 -245 653.25 -49 653.5 -48 653.75 67 654 494 654.25 -23 654.5 36 654.75 207 655 -218 655.25 150 655.5 112 655.75 -160 656 154 656.25 262 656.5 -32 656.75 -7 657 115 657.25 -364 657.5 279 657.75 293 658 -326 658.25 53 658.5 258 658.75 22 659 106 659.25 109 659.5 86 659.75 401 660 -384 660.25 -261 660.5 -275 660.75 9 661 -25 661.25 -298 661.5 529 661.75 42 662 85 662.25 -112 662.5 394 662.75 411 663 -219 663.25 180 663.5 -129 663.75 179 664 41 664.25 -126 664.5 214 664.75 89 665 235 665.25 151 665.5 -111 665.75 118 666 29 666.25 0 666.5 422 666.75 -354 667 -90 667.25 -135 667.5 217 667.75 -450 668 287 668.25 393 668.5 350 668.75 71 669 53 669.25 336 669.5 6 669.75 -119 670 571 670.25 509 670.5 -422 670.75 114 671 -277 671.25 531 671.5 -751 671.75 299 672 61 672.25 -104 672.5 -78 672.75 250 673 171 673.25 330 673.5 -25 673.75 -34 674 -204 674.25 37 674.5 -23 674.75 1 675 -121 675.25 456 675.5 221 675.75 -81 676 -243 676.25 206 676.5 504 676.75 46 677 -217 677.25 -23 677.5 77 677.75 -161 678 229 678.25 341 678.5 107 678.75 119 679 322 679.25 -445 679.5 274 679.75 488 680 287 680.25 -232 680.5 -328 680.75 -57 681 86 681.25 -90 681.5 -265 681.75 198 682 24 682.25 -457 682.5 -47 682.75 112 683 187 683.25 -136 683.5 142 683.75 272 684 291 684.25 -201 684.5 -255 684.75 -182 685 115 685.25 -331 685.5 -74 685.75 -175 686 -426 686.25 294 686.5 -191 686.75 -227 687 -151 687.25 16 687.5 348 687.75 -471 688 1 688.25 -320 688.5 41 688.75 -65 689 63 689.25 293 689.5 46 689.75 -200 690 -3 690.25 66 690.5 -173 690.75 -404 691 218 691.25 -309 691.5 142 691.75 -177 692 194 692.25 218 692.5 -63 692.75 -37 693 -118 693.25 -377 693.5 -208 693.75 144 694 -325 694.25 -25 694.5 -117 694.75 -111 695 323 695.25 332 695.5 -258 695.75 -531 696 -755 696.25 -128 696.5 -321 696.75 127 697 -5 697.25 584 697.5 -302 697.75 -100 698 282 698.25 141 698.5 106 698.75 -393 699 -326 699.25 0 699.5 -113 699.75 -77 700 -300