# Emission spectrum of in 0.5 M H2SO4 # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by on in the summer of 1995 # using a Spex FluoroMax. The excitation and emission monochromators were set at 1 mm, giving a spectral bandwidth of 4.25 nm. The data interval was 0.5 nm and the integration time was 2.0 sec. Samples were prepared in 1cm pathlength quartz cells with absorbance less than 0.1 at the excitation and all emission wavelengths to uniformly illuminate across the sample, and to avoid the inner-filter effect. The dark counts were subtracted and the spectra were corrected for wavelength-dependent instrument sensitivity. # ##Wavelength (nm) Emission (AU) 320 2281 320.5 2181 321 2175 321.5 2133 322 2121 322.5 2030 323 2084 323.5 2080 324 1973 324.5 2075 325 2125 325.5 2131 326 2124 326.5 2075 327 2091 327.5 2031 328 1953 328.5 2044 329 2184 329.5 1955 330 2073 330.5 1997 331 1981 331.5 1991 332 2019 332.5 2037 333 2071 333.5 1949 334 2036 334.5 2016 335 1977 335.5 2027 336 2020 336.5 2068 337 2039 337.5 2201 338 2251 338.5 2384 339 2440 339.5 2927 340 3059 340.5 3699 341 4179 341.5 5055 342 5745 342.5 6684 343 7479 343.5 8360 344 9407 344.5 9840 345 10201 345.5 10390 346 10544 346.5 10122 347 9839 347.5 9079 348 8229 348.5 7116 349 6263 349.5 5233 350 4554 350.5 3830 351 3333 351.5 2705 352 2610 352.5 2399 353 2221 353.5 2253 354 2097 354.5 2263 355 2218 355.5 2240 356 2158 356.5 2242 357 2144 357.5 2198 358 2337 358.5 2235 359 2227 359.5 2333 360 2356 360.5 2563 361 2444 361.5 2683 362 2611 362.5 2863 363 2955 363.5 3008 364 3142 364.5 3412 365 3549 365.5 3837 366 4128 366.5 4329 367 4667 367.5 5038 368 5238 368.5 5752 369 5946 369.5 6745 370 7139 370.5 7651 371 8374 371.5 9226 372 10062 372.5 11082 373 11862 373.5 12914 374 13706 374.5 15330 375 16082 375.5 18339 376 19429 376.5 21674 377 23419 377.5 25898 378 27814 378.5 30838 379 32688 379.5 36923 380 38961 380.5 42568 381 45621 381.5 50937 382 53543 382.5 59270 383 63413 383.5 70228 384 74002 384.5 80896 385 85941 385.5 95808 386 100075 386.5 109297 387 115835 387.5 127700 388 132832 388.5 144096 389 152316 389.5 165122 390 172334 390.5 184146 391 191923 391.5 206468 392 215380 392.5 229522 393 238909 393.5 256452 394 264660 394.5 280807 395 292369 395.5 310903 396 321926 396.5 337232 397 350524 397.5 370166 398 381733 398.5 400767 399 413848 399.5 437790 400 451603 400.5 471147 401 483912 401.5 511461 402 523055 402.5 545215 403 560394 403.5 589495 404 604237 404.5 627045 405 643460 405.5 678311 406 692439 406.5 722875 407 742917 407.5 778883 408 792766 408.5 821049 409 846161 409.5 880305 410 895378 410.5 926545 411 947605 411.5 980451 412 995351 412.5 1021701 413 1041357 413.5 1074101 414 1088811 414.5 1113170 415 1133364 415.5 1163363 416 1178283 416.5 1205510 417 1224503 417.5 1258939 418 1268136 418.5 1294770 419 1319152 419.5 1345360 420 1358315 420.5 1382288 421 1407324 421.5 1431855 422 1446909 422.5 1473928 423 1489268 423.5 1516672 424 1532743 424.5 1555275 425 1575196 425.5 1593824 426 1617423 426.5 1640678 427 1654585 427.5 1679729 428 1691094 428.5 1716570 429 1728504 429.5 1757626 430 1767316 430.5 1786297 431 1803027 431.5 1824190 432 1833171 432.5 1849754 433 1861380 433.5 1885376 434 1898917 434.5 1908920 435 1919955 435.5 1935792 436 1940502 436.5 1956126 437 1962567 437.5 1973844 438 1981945 438.5 1991856 439 2001829 439.5 2006503 440 2022301 440.5 2026296 441 2028185 441.5 2043288 442 2047012 442.5 2055358 443 2063902 443.5 2071054 444 2075214 444.5 2077171 445 2087976 445.5 2089010 446 2094813 446.5 2095598 447 2100185 447.5 2106433 448 2106650 448.5 2104651 449 2112311 449.5 2110937 450 2111394 450.5 2109571 451 2114415 451.5 2111157 452 2106323 452.5 2113838 453 2106578 453.5 2101827 454 2106674 454.5 2099943 455 2099573 455.5 2091466 456 2087621 456.5 2088939 457 2082004 457.5 2076582 458 2070829 458.5 2062576 459 2056803 459.5 2042820 460 2047611 460.5 2038843 461 2035336 461.5 2025322 462 2023044 462.5 2017491 463 2004979 463.5 1996031 464 1990110 464.5 1983785 465 1979172 465.5 1964159 466 1967267 466.5 1953132 467 1947229 467.5 1936273 468 1931617 468.5 1918285 469 1910536 469.5 1900605 470 1895311 470.5 1886174 471 1878382 471.5 1863258 472 1861710 472.5 1848459 473 1839928 473.5 1828934 474 1822824 474.5 1806764 475 1798805 475.5 1782589 476 1780090 476.5 1763788 477 1753484 477.5 1730645 478 1729738 478.5 1706604 479 1692376 479.5 1678256 480 1670853 480.5 1653553 481 1647147 481.5 1627837 482 1618623 482.5 1606353 483 1592124 483.5 1572231 484 1568348 484.5 1553255 485 1544612 485.5 1529931 486 1519791 486.5 1506386 487 1495218 487.5 1482477 488 1473545 488.5 1459846 489 1444732 489.5 1431975 490 1426928 490.5 1409764 491 1402359 491.5 1384869 492 1379777 492.5 1361501 493 1351411 493.5 1341712 494 1331609 494.5 1316615 495 1309431 495.5 1289553 496 1285405 496.5 1269725 497 1257902 497.5 1244259 498 1235220 498.5 1223225 499 1212461 499.5 1197916 500 1189137 500.5 1174565 501 1164506 501.5 1148754 502 1141238 502.5 1124609 503 1118343 503.5 1097335 504 1091489 504.5 1075798 505 1066900 505.5 1051580 506 1043887 506.5 1030209 507 1019606 507.5 1004322 508 997564 508.5 986826 509 976207 509.5 960196 510 960231 510.5 948312 511 935121 511.5 922812 512 915821 512.5 905655 513 896099 513.5 882514 514 877670 514.5 866843 515 859401 515.5 845016 516 841539 516.5 831188 517 821887 517.5 808601 518 806285 518.5 794342 519 786987 519.5 776193 520 768871 520.5 756820 521 751145 521.5 739840 522 736959 522.5 724092 523 716491 523.5 706362 524 703370 524.5 690815 525 682289 525.5 673302 526 664728 526.5 658304 527 651014 527.5 636870 528 637305 528.5 622699 529 616230 529.5 605065 530 602805 530.5 593068 531 585570 531.5 575988 532 570078 532.5 564199 533 556587 533.5 547866 534 542272 534.5 536734 535 530645 535.5 521050 536 516767 536.5 510500 537 505027 537.5 495899 538 494286 538.5 486969 539 481882 539.5 474191 540 468990 540.5 462136 541 458472 541.5 450963 542 447738 542.5 441028 543 436851 543.5 426921 544 424248 544.5 418841 545 415143 545.5 407036 546 402986 546.5 396425 547 393482 547.5 387593 548 382985 548.5 376405 549 375580 549.5 367464 550 363949 550.5 359827 551 354293 551.5 348503 552 344013 552.5 339187 553 333571 553.5 329949 554 326565 554.5 320257 555 316266 555.5 312021 556 309111 556.5 304336 557 302464 557.5 297034 558 293749 558.5 289562 559 285592 559.5 281347 560 279207 560.5 275338 561 272477 561.5 267178 562 264620 562.5 261740 563 258829 563.5 253167 564 251302 564.5 247426 565 245912 565.5 242308 566 237949 566.5 235529 567 232047 567.5 227743 568 227393 568.5 222848 569 222440 569.5 217347 570 215524 570.5 212062 571 210004 571.5 206347 572 203422 572.5 200171 573 198311 573.5 195473 574 195370 574.5 191522 575 188480 575.5 186254 576 183891 576.5 181109 577 178900 577.5 176202 578 174606 578.5 169736 579 169341 579.5 165173 580 164304 580.5 162826 581 161116 581.5 157138 582 155870 582.5 154549 583 152869 583.5 149688 584 149262 584.5 146467 585 144038 585.5 142865 586 140846 586.5 138827 587 136914 587.5 134659 588 133524 588.5 130691 589 130342 589.5 128304 590 125502 590.5 125953 591 124360 591.5 121478 592 120564 592.5 119129 593 116378 593.5 116478 594 114275 594.5 113511 595 111401 595.5 110368 596 108451 596.5 106886 597 105675 597.5 103110 598 103232 598.5 100672 599 100506 599.5 99162 600 96342