# Emission spectrum of in water, 0.1 M phosphate buffer, pH 7 # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by on in the summer of 1995 # using a Spex FluoroMax. The excitation and emission monochromators were set at 1 mm, giving a spectral bandwidth of 4.25 nm. The data interval was 0.5 nm and the integration time was 2.0 sec. Samples were prepared in 1cm pathlength quartz cells with absorbance less than 0.1 at the excitation and all emission wavelengths to uniformly illuminate across the sample, and to avoid the inner-filter effect. The dark counts were subtracted and the spectra were corrected for wavelength-dependent instrument sensitivity. # ##Wavelength (nm) Emission (AU) 270 152 270.5 159 271 200 271.5 220 272 217 272.5 218 273 245 273.5 215 274 281 274.5 279 275 371 275.5 444 276 517 276.5 728 277 769 277.5 1115 278 1238 278.5 1690 279 1919 279.5 2628 280 3257 280.5 4148 281 4954 281.5 6658 282 7642 282.5 9729 283 11301 283.5 13909 284 14980 284.5 17194 285 18538 285.5 20041 286 20782 286.5 21859 287 22714 287.5 23884 288 24757 288.5 25728 289 27165 289.5 29016 290 29411 290.5 31023 291 32569 291.5 33611 292 34678 292.5 36503 293 37207 293.5 38517 294 38988 294.5 40492 295 41113 295.5 42044 296 42818 296.5 43396 297 44166 297.5 44761 298 45021 298.5 45309 299 46001 299.5 46701 300 46838 300.5 47203 301 47571 301.5 47282 302 47277 302.5 47601 303 48203 303.5 47438 304 47367 304.5 47200 305 47403 305.5 46570 306 46484 306.5 45745 307 45632 307.5 44829 308 44725 308.5 44125 309 43514 309.5 42565 310 42231 310.5 41038 311 40701 311.5 39752 312 39054 312.5 38487 313 37646 313.5 36693 314 36152 314.5 35286 315 34621 315.5 33291 316 32812 316.5 32155 317 31421 317.5 30203 318 29989 318.5 29192 319 28576 319.5 27619 320 27347 320.5 26215 321 25812 321.5 25081 322 24094 322.5 23729 323 23273 323.5 22388 324 21998 324.5 21406 325 20960 325.5 20203 326 19688 326.5 18971 327 18896 327.5 17910 328 17728 328.5 17017 329 16607 329.5 16065 330 15750 330.5 14996 331 14907 331.5 13955 332 13840 332.5 13315 333 13049 333.5 12306 334 12189 334.5 11662 335 11482 335.5 10909 336 10737 336.5 10352 337 10207 337.5 9864 338 9464 338.5 9086 339 8895 339.5 8550 340 8215 340.5 8024 341 7980 341.5 7492 342 7340 342.5 7238 343 7130 343.5 6834 344 6779 344.5 6397 345 6281 345.5 6079 346 5975 346.5 5774 347 5550 347.5 5489 348 5342 348.5 5365 349 5003 349.5 4896 350 4768 350.5 4745 351 4658 351.5 4332 352 4418 352.5 4147 353 4048 353.5 4062 354 3819 354.5 3792 355 3759 355.5 3570 356 3483 356.5 3372 357 3240 357.5 3109 358 3165 358.5 3014 359 2886 359.5 2867 360 2850 360.5 2585 361 2712 361.5 2591 362 2508 362.5 2391 363 2370 363.5 2262 364 2321 364.5 2087 365 2155 365.5 1942 366 1980 366.5 1950 367 2008 367.5 1898 368 1894 368.5 1836 369 1778 369.5 1743 370 1691 370.5 1683 371 1667 371.5 1561 372 1595 372.5 1565 373 1602 373.5 1501 374 1414 374.5 1442 375 1386 375.5 1316 376 1326 376.5 1309 377 1287 377.5 1316 378 1268 378.5 1254 379 1259 379.5 1162 380 1197 380.5 1171 381 1174 381.5 1120 382 1078 382.5 1097 383 1051 383.5 1042 384 992 384.5 1048 385 1114 385.5 1031 386 1017 386.5 959 387 845 387.5 856 388 878 388.5 880 389 884 389.5 900 390 861 390.5 877 391 887 391.5 843 392 862 392.5 763 393 783 393.5 787 394 789 394.5 766 395 759 395.5 896 396 846 396.5 800 397 813 397.5 718 398 816 398.5 746 399 764 399.5 703 400 754 400.5 705 401 686 401.5 710 402 747 402.5 733 403 661 403.5 748 404 721 404.5 662 405 672 405.5 709 406 705 406.5 672 407 650 407.5 643 408 690 408.5 643 409 635 409.5 633 410 720 410.5 650 411 675 411.5 593 412 697 412.5 609 413 547 413.5 607 414 629 414.5 591 415 632 415.5 589 416 683 416.5 593 417 664 417.5 646 418 656 418.5 512 419 620 419.5 600 420 577 420.5 627 421 599 421.5 603 422 570 422.5 584 423 598 423.5 612 424 561 424.5 529 425 476 425.5 583 426 582 426.5 537 427 539 427.5 579 428 593 428.5 461 429 515 429.5 526 430 555 430.5 501 431 580 431.5 543 432 472 432.5 540 433 543 433.5 595 434 557 434.5 557 435 499 435.5 436 436 508 436.5 481 437 491 437.5 531 438 519 438.5 441 439 507 439.5 445 440 489 440.5 507 441 463 441.5 462 442 472 442.5 423 443 436 443.5 455 444 440 444.5 466 445 466 445.5 403 446 464 446.5 438 447 463 447.5 534 448 454 448.5 427 449 410 449.5 471 450 485 450.5 450 451 434 451.5 419 452 400 452.5 406 453 386 453.5 421 454 447 454.5 369 455 397 455.5 391 456 392 456.5 355 457 351 457.5 399 458 346 458.5 366 459 350 459.5 374 460 295 460.5 347 461 377 461.5 362 462 414 462.5 402 463 351 463.5 360 464 410 464.5 413 465 329 465.5 377 466 398 466.5 334 467 330 467.5 321 468 358 468.5 397 469 363 469.5 325 470 320 470.5 385 471 328 471.5 341 472 306 472.5 384 473 346 473.5 313 474 356 474.5 329 475 326 475.5 367 476 368 476.5 331 477 377 477.5 393 478 308 478.5 380 479 332 479.5 375 480 361 480.5 309 481 343 481.5 366 482 392 482.5 355 483 361 483.5 398 484 380 484.5 337 485 370 485.5 334 486 326 486.5 333 487 379 487.5 386 488 441 488.5 340 489 398 489.5 387 490 326 490.5 329 491 312 491.5 382 492 337 492.5 344 493 382 493.5 350 494 362 494.5 362 495 362 495.5 322 496 380 496.5 366 497 372 497.5 346 498 346 498.5 332 499 383 499.5 313 500 313