# Emission spectrum of in toluene # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by on in 1994 # using a Spex FluoroMax. The excitation and emission monochromators were set at 1 mm, giving a spectral bandwidth of 4.25 nm. The data interval was 0.5 nm and the integration time was 2.0 sec. Samples were prepared in 1cm pathlength quartz cells with absorbance less than 0.1 at the excitation and all emission wavelengths to uniformly illuminate across the sample, and to avoid the inner-filter effect. The dark counts were subtracted and the spectra were corrected for wavelength-dependent instrument sensitivity. # ##Wavelength (nm) Emission (AU) 570 2389 571 2811 572 2915 573 2949 574 3163 575 3207 576 3529 577 4003 578 4169 579 4772 580 5451 581 6333 582 7370 583 8407 584 10230 585 12269 586 15109 587 18303 588 22440 589 26224 590 30216 591 34188 592 38433 593 42423 594 47464 595 51006 596 56274 597 61022 598 65567 599 70666 600 74492 601 76740 602 79179 603 79246 604 81670 605 83564 606 87625 607 92219 608 97716 609 101831 610 105891 611 108546 612 108504 613 108525 614 107904 615 105918 616 104772 617 103148 618 103918 619 103606 620 104018 621 106615 622 109800 623 114807 624 122093 625 132951 626 147976 627 167519 628 196659 629 235264 630 292274 631 354847 632 442544 633 545212 634 666338 635 803300 636 972089 637 1178808 638 1452532 639 1768556 640 2239396 641 2849920 642 3742449 643 4830364 644 6300587 645 7890072 646 9696045 647 11170070 648 12446660 649 13120380 650 13229740 651 12861100 652 12091260 653 11224290 654 10231040 655 9421284 656 8630734 657 7963846 658 7430593 659 7058669 660 6762125 661 6547518 662 6300464 663 6074472 664 5711986 665 5327853 666 4890443 667 4503979 668 4075034 669 3726239 670 3403202 671 3148153 672 2896287 673 2723228 674 2577262 675 2479729 676 2412819 677 2397116 678 2382632 679 2392799 680 2410503 681 2452065 682 2512111 683 2580012 684 2668284 685 2752788 686 2863393 687 2961469 688 3077323 689 3209512 690 3357935 691 3489895 692 3618268 693 3720790 694 3809746 695 3874929 696 3928311 697 4002889 698 4134783 699 4306116 700 4591020 701 4969954 702 5501824 703 6026584 704 6715470 705 7395282 706 8116804 707 8758819 708 9344379 709 9830441 710 10187950 711 10433990 712 10653360 713 10836450 714 11075510 715 11361480 716 11780050 717 12301550 718 12851540 719 13304890 720 13642760 721 13746490 722 13479480 723 13001580 724 12154050 725 11279060 726 10224710 727 9356534 728 8394619 729 7579121 730 6783683 731 6111433 732 5524235 733 5017718 734 4606853 735 4323070 736 4016480 737 3762451 738 3509182 739 3301457 740 3046548 741 2814556 742 2560523 743 2347595 744 2114821 745 1914247 746 1710399 747 1555185 748 1406565 749 1306278 750 1200381 751 1120003 752 1044340 753 983836 754 922812 755 887539 756 846201 757 810480 758 777796 759 757938 760 732396 761 708363 762 680257 763 675226 764 654997 765 648012 766 633971 767 624365 768 619334 769 609351 770 601723 771 607074 772 602640 773 602014 774 601452 775 610729 776 628212 777 628067 778 635184 779 641816 780 653398 781 652371 782 651883 783 649230 784 650627 785 648178 786 640249 787 636833 788 638165 789 628669 790 633976 791 634458 792 637723 793 642947 794 647796 795 637967 796 645751 797 636680 798 619336 799 593226 800 575709