# Optical absorption spectrum of Magnesium tetramesitylporphyrin, [MgTMP] in toluene # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by R. W. Wagner in 1995 using a Cary 3. # The absorption values were collected using a spectral bandwidth of 1.0 nm, a signal averaging time of 0.133 sec, a data interval of 0.25 nm, and a scan rate of 112.5 nm/min. # # These measurements were scaled to make the molar extinction coefficient match # the value of 446700 cm-1/M at 426.5 nm. These values were # then interpolated to report extinction coefficients at regular 1nm intervals # # The reported molar extinction coefficient is from # Lindsey, J. S. and J. N. Woodford (1995) A simple method for preparing magnesium porphyrins. Inorg. Chem. 34, 1063-1069. # ##Wavelength (nm) Molar Extinction (cm-1/M) 349.75 8840 350 5073 350.25 4755 350.5 4291 350.75 6081 351 7275 351.25 5200 351.5 4787 351.75 8537 352 4361 352.25 5806 352.5 6124 352.75 8578 353 4018 353.25 7326 353.5 7728 353.75 8105 354 6965 354.25 7409 354.5 7334 354.75 5096 355 7206 355.25 6234 355.5 6940 355.75 7040 356 5426 356.25 5283 356.5 3875 356.75 5740 357 4684 357.25 6325 357.5 4988 357.75 5874 358 4317 358.25 6228 358.5 6197 358.75 7392 359 4646 359.25 5593 359.5 3492 359.75 4743 360 7238 360.25 6289 360.5 5691 360.75 5988 361 5733 361.25 5401 361.5 6086 361.75 4719 362 5771 362.25 3051 362.5 4829 362.75 5687 363 4585 363.25 4082 363.5 3511 363.75 6172 364 4621 364.25 4734 364.5 6594 364.75 6046 365 7524 365.25 4193 365.5 3695 365.75 4883 366 5619 366.25 2555 366.5 5329 366.75 6386 367 4977 367.25 6914 367.5 4486 367.75 5411 368 5522 368.25 4358 368.5 5451 368.75 4919 369 6398 369.25 4471 369.5 4112 369.75 4972 370 5036 370.25 5826 370.5 2994 370.75 4893 371 5186 371.25 5492 371.5 6857 371.75 5485 372 5615 372.25 3931 372.5 7132 372.75 5705 373 5774 373.25 7096 373.5 5217 373.75 5952 374 5342 374.25 3374 374.5 5500 374.75 4451 375 4008 375.25 5642 375.5 5038 375.75 2929 376 6562 376.25 4552 376.5 4705 376.75 6140 377 4072 377.25 5333 377.5 6877 377.75 4654 378 3674 378.25 5001 378.5 4901 378.75 3957 379 3340 379.25 4765 379.5 6686 379.75 4263 380 3573 380.25 5416 380.5 3316 380.75 5229 381 4861 381.25 4951 381.5 3231 381.75 5214 382 4974 382.25 5080 382.5 4781 382.75 5067 383 5150 383.25 4823 383.5 4606 383.75 5028 384 4209 384.25 4593 384.5 5651 384.75 5582 385 5532 385.25 6607 385.5 6760 385.75 5144 386 4448 386.25 6686 386.5 5945 386.75 6252 387 5635 387.25 5327 387.5 8438 387.75 6723 388 5824 388.25 6132 388.5 5609 388.75 5064 389 6376 389.25 6489 389.5 7870 389.75 6979 390 7688 390.25 6635 390.5 6264 390.75 6034 391 6721 391.25 6943 391.5 5631 391.75 6155 392 6265 392.25 5102 392.5 7661 392.75 7125 393 8266 393.25 6842 393.5 6581 393.75 6263 394 7153 394.25 7979 394.5 6665 394.75 7825 395 7239 395.25 10552 395.5 8675 395.75 8215 396 9524 396.25 9381 396.5 10131 396.75 10227 397 11234 397.25 12533 397.5 12494 397.75 13017 398 14687 398.25 14055 398.5 13195 398.75 14886 399 16969 399.25 17674 399.5 16875 399.75 17723 400 17874 400.25 19169 400.5 19441 400.75 22857 401 23982 401.25 24198 401.5 23385 401.75 26528 402 26258 402.25 27631 402.5 28880 402.75 29064 403 27954 403.25 29399 403.5 30303 403.75 31547 404 32311 404.25 32393 404.5 32317 404.75 31964 405 31435 405.25 31496 405.5 30504 405.75 32121 406 30804 406.25 30752 406.5 29428 406.75 29739 407 28980 407.25 29089 407.5 28945 407.75 29578 408 27491 408.25 28814 408.5 27868 408.75 26819 409 25637 409.25 26878 409.5 25014 409.75 25162 410 26408 410.25 25199 410.5 25542 410.75 23546 411 23846 411.25 24509 411.5 22676 411.75 25033 412 22215 412.25 23464 412.5 24066 412.75 23611 413 25281 413.25 26128 413.5 26551 413.75 26234 414 27851 414.25 27838 414.5 27355 414.75 29688 415 30407 415.25 32284 415.5 31602 415.75 34306 416 38099 416.25 40533 416.5 42915 416.75 46354 417 50900 417.25 52471 417.5 56651 417.75 61049 418 66199 418.25 70254 418.5 76744 418.75 82542 419 86840 419.25 90655 419.5 98209 419.75 101880 420 107399 420.25 113041 420.5 119239 420.75 125442 421 132713 421.25 140678 421.5 147186 421.75 158082 422 167652 422.25 179338 422.5 193143 422.75 208065 423 224903 423.25 242312 423.5 260474 423.75 280793 424 300821 424.25 323191 424.5 343429 424.75 362042 425 381965 425.25 398970 425.5 412802 425.75 427518 426 436520 426.25 442502 426.5 446699 426.75 446326 427 444010 427.25 438679 427.5 429422 427.75 418482 428 405048 428.25 390139 428.5 371982 428.75 353585 429 332578 429.25 312513 429.5 295249 429.75 273993 430 253613 430.25 234376 430.5 214308 430.75 199211 431 182077 431.25 165214 431.5 152624 431.75 136611 432 126583 432.25 111473 432.5 104275 432.75 92747 433 85099 433.25 77277 433.5 69646 433.75 63003 434 59114 434.25 52802 434.5 49075 434.75 43898 435 38928 435.25 35879 435.5 31097 435.75 28508 436 24442 436.25 22625 436.5 20222 436.75 19329 437 18698 437.25 17173 437.5 15615 437.75 15214 438 13520 438.25 12724 438.5 10983 438.75 10172 439 10340 439.25 10097 439.5 9638 439.75 8385 440 8266 440.25 8454 440.5 7855 440.75 8686 441 7094 441.25 7429 441.5 7900 441.75 7594 442 7526 442.25 6954 442.5 7312 442.75 5610 443 5835 443.25 5860 443.5 6819 443.75 5475 444 5516 444.25 6193 444.5 4930 444.75 5728 445 5838 445.25 5020 445.5 5000 445.75 4758 446 4146 446.25 4945 446.5 5763 446.75 3528 447 3193 447.25 5481 447.5 4595 447.75 5691 448 3829 448.25 4151 448.5 4385 448.75 4662 449 4763 449.25 3073 449.5 3807 449.75 2615 450 3503 450.25 2289 450.5 2798 450.75 2593 451 2372 451.25 3299 451.5 2407 451.75 2006 452 2569 452.25 2368 452.5 2062 452.75 2461 453 2235 453.25 2157 453.5 2452 453.75 2032 454 910 454.25 2267 454.5 1404 454.75 1279 455 670 455.25 1274 455.5 1594 455.75 2133 456 1072 456.25 2542 456.5 1683 456.75 1805 457 1768 457.25 2057 457.5 1208 457.75 1119 458 737 458.25 1088 458.5 32 458.75 -80 459 1171 459.25 820 459.5 1216 459.75 1755 460 797 460.25 1481 460.5 2521 460.75 193 461 1002 461.25 1242 461.5 2128 461.75 999 462 902 462.25 207 462.5 1185 462.75 1284 463 856 463.25 943 463.5 1396 463.75 1574 464 1094 464.25 914 464.5 664 464.75 489 465 1436 465.25 908 465.5 148 465.75 651 466 1045 466.25 705 466.5 754 466.75 1101 467 1162 467.25 596 467.5 1669 467.75 1178 468 963 468.25 38 468.5 991 468.75 187 469 807 469.25 111 469.5 1665 469.75 1349 470 1335 470.25 194 470.5 335 470.75 922 471 1240 471.25 130 471.5 1428 471.75 827 472 896 472.25 420 472.5 670 472.75 1280 473 715 473.25 266 473.5 723 473.75 1022 474 1185 474.25 14 474.5 557 474.75 45 475 1085 475.25 795 475.5 1604 475.75 1200 476 1214 476.25 1380 476.5 -60 476.75 975 477 879 477.25 518 477.5 1372 477.75 504 478 906 478.25 464 478.5 505 478.75 1569 479 302 479.25 474 479.5 1324 479.75 1950 480 905 480.25 388 480.5 310 480.75 1799 481 540 481.25 623 481.5 140 481.75 127 482 407 482.25 1868 482.5 1155 482.75 199 483 1072 483.25 2290 483.5 542 483.75 993 484 1499 484.25 1373 484.5 -46 484.75 338 485 1176 485.25 788 485.5 235 485.75 1325 486 1607 486.25 269 486.5 710 486.75 677 487 1927 487.25 1155 487.5 1517 487.75 938 488 788 488.25 1055 488.5 838 488.75 1814 489 1097 489.25 522 489.5 1358 489.75 290 490 946 490.25 123 490.5 1266 490.75 1222 491 1396 491.25 -95 491.5 1254 491.75 1397 492 1548 492.25 721 492.5 1780 492.75 1554 493 1372 493.25 1535 493.5 2046 493.75 737 494 1079 494.25 2215 494.5 1260 494.75 634 495 -177 495.25 639 495.5 801 495.75 1218 496 1645 496.25 534 496.5 1049 496.75 1720 497 1229 497.25 1022 497.5 1844 497.75 763 498 867 498.25 2108 498.5 1625 498.75 1107 499 472 499.25 477 499.5 -99 499.75 1275 500 1839 500.25 1898 500.5 1973 500.75 2528 501 513 501.25 768 501.5 1141 501.75 1155 502 1591 502.25 1045 502.5 471 502.75 1425 503 1239 503.25 340 503.5 1803 503.75 836 504 1208 504.25 1381 504.5 1717 504.75 2373 505 1152 505.25 1878 505.5 645 505.75 1835 506 1732 506.25 1083 506.5 1486 506.75 1585 507 1463 507.25 1892 507.5 1487 507.75 1749 508 1652 508.25 1963 508.5 1902 508.75 63 509 2170 509.25 1944 509.5 1355 509.75 1885 510 1282 510.25 553 510.5 964 510.75 1675 511 1680 511.25 2076 511.5 1527 511.75 2138 512 1760 512.25 1651 512.5 2607 512.75 1888 513 2036 513.25 1429 513.5 965 513.75 2139 514 1551 514.25 2785 514.5 2289 514.75 2544 515 2639 515.25 3237 515.5 1031 515.75 2796 516 2657 516.25 1051 516.5 1359 516.75 1650 517 1461 517.25 1732 517.5 1378 517.75 2789 518 2481 518.25 2785 518.5 1922 518.75 2205 519 2833 519.25 2303 519.5 2777 519.75 1376 520 1955 520.25 1548 520.5 2682 520.75 2665 521 2307 521.25 1486 521.5 1791 521.75 2222 522 2461 522.25 3013 522.5 1944 522.75 2881 523 2352 523.25 2429 523.5 3100 523.75 2682 524 2422 524.25 1849 524.5 1894 524.75 1225 525 1655 525.25 2691 525.5 2134 525.75 1696 526 2139 526.25 2822 526.5 3606 526.75 2561 527 3299 527.25 1896 527.5 2542 527.75 1976 528 1365 528.25 1858 528.5 2697 528.75 1276 529 2711 529.25 1834 529.5 2604 529.75 1545 530 2242 530.25 2728 530.5 3114 530.75 2494 531 2391 531.25 1244 531.5 2326 531.75 2027 532 2486 532.25 1982 532.5 2051 532.75 1259 533 1036 533.25 2135 533.5 1419 533.75 1500 534 1627 534.25 2418 534.5 2460 534.75 2026 535 2001 535.25 1968 535.5 1211 535.75 1532 536 1870 536.25 1490 536.5 1373 536.75 1260 537 775 537.25 1818 537.5 1578 537.75 2240 538 2262 538.25 2515 538.5 1457 538.75 2036 539 1874 539.25 1672 539.5 1952 539.75 1521 540 2186 540.25 1393 540.5 2211 540.75 1818 541 2096 541.25 1971 541.5 1851 541.75 2193 542 1642 542.25 2656 542.5 2076 542.75 1106 543 2748 543.25 2939 543.5 2511 543.75 2180 544 3468 544.25 2037 544.5 1411 544.75 2543 545 1831 545.25 2545 545.5 2288 545.75 3411 546 2534 546.25 3582 546.5 2403 546.75 3112 547 3469 547.25 3163 547.5 2645 547.75 3307 548 3425 548.25 2383 548.5 3496 548.75 3063 549 3628 549.25 3193 549.5 4411 549.75 3628 550 3176 550.25 4117 550.5 4310 550.75 4688 551 4589 551.25 4825 551.5 4610 551.75 5371 552 5420 552.25 5833 552.5 5538 552.75 6088 553 6032 553.25 6509 553.5 6903 553.75 7541 554 6359 554.25 6837 554.5 7108 554.75 7482 555 8865 555.25 8527 555.5 7615 555.75 7906 556 8967 556.25 8839 556.5 9435 556.75 9276 557 9940 557.25 10013 557.5 10072 557.75 10003 558 10940 558.25 10558 558.5 10365 558.75 10750 559 10866 559.25 10514 559.5 11379 559.75 10752 560 12267 560.25 11508 560.5 12735 560.75 12502 561 11806 561.25 12464 561.5 12150 561.75 12716 562 12264 562.25 12946 562.5 14083 562.75 13968 563 14254 563.25 13067 563.5 15008 563.75 14436 564 13281 564.25 14242 564.5 15435 564.75 15005 565 15358 565.25 15106 565.5 15249 565.75 15008 566 14605 566.25 14623 566.5 14912 566.75 14907 567 14125 567.25 13356 567.5 14006 567.75 13490 568 14722 568.25 14144 568.5 12753 568.75 11930 569 12993 569.25 12189 569.5 12551 569.75 11609 570 12803 570.25 10849 570.5 10854 570.75 11569 571 10086 571.25 10081 571.5 10111 571.75 9355 572 9657 572.25 9337 572.5 8334 572.75 7219 573 8252 573.25 8676 573.5 8381 573.75 8045 574 7469 574.25 6892 574.5 7492 574.75 6423 575 6404 575.25 6819 575.5 7205 575.75 6737 576 5829 576.25 6867 576.5 5888 576.75 5651 577 6323 577.25 5631 577.5 5488 577.75 5102 578 4923 578.25 5182 578.5 5036 578.75 4685 579 4245 579.25 3969 579.5 3505 579.75 4386 580 3661 580.25 3017 580.5 3994 580.75 4385 581 2427 581.25 3604 581.5 3621 581.75 3408 582 3099 582.25 1978 582.5 1684 582.75 3175 583 3194 583.25 3852 583.5 2693 583.75 2918 584 2942 584.25 2401 584.5 3116 584.75 2810 585 1922 585.25 2410 585.5 3354 585.75 1577 586 2085 586.25 2092 586.5 1362 586.75 1377 587 1980 587.25 2133 587.5 2463 587.75 2472 588 1927 588.25 2164 588.5 2441 588.75 1476 589 2307 589.25 2197 589.5 2847 589.75 1533 590 1437 590.25 2272 590.5 1904 590.75 2544 591 1728 591.25 2499 591.5 1759 591.75 2388 592 2594 592.25 2195 592.5 1885 592.75 2214 593 1583 593.25 1568 593.5 1667 593.75 2689 594 2591 594.25 1990 594.5 1648 594.75 2887 595 3341 595.25 1379 595.5 2861 595.75 3589 596 2673 596.25 2625 596.5 1083 596.75 2603 597 2717 597.25 3169 597.5 2696 597.75 3706 598 3479 598.25 4212 598.5 3563 598.75 3704 599 4050 599.25 3784 599.5 5514 599.75 4711 600 3691 600.25 4047 600.5 5314 600.75 5290 601 5498 601.25 4951 601.5 5645 601.75 5278 602 5823 602.25 5163 602.5 6257 602.75 5801 603 5346 603.25 6244 603.5 5185 603.75 5650 604 5076 604.25 5071 604.5 5927 604.75 5458 605 6287 605.25 5732 605.5 4849 605.75 4600 606 4480 606.25 5121 606.5 5620 606.75 4336 607 4031 607.25 4843 607.5 4680 607.75 3226 608 3776 608.25 3640 608.5 4500 608.75 3732 609 3344 609.25 2708 609.5 2910 609.75 3125 610 3270 610.25 2505 610.5 937 610.75 2127 611 2757 611.25 2929 611.5 2212 611.75 1683 612 3193 612.25 2203 612.5 1320 612.75 2054 613 863 613.25 2489 613.5 1436 613.75 1482 614 2060 614.25 2252 614.5 1670 614.75 2441 615 1141 615.25 1933 615.5 1159 615.75 1583 616 1925 616.25 2147 616.5 527 616.75 344 617 820 617.25 1858 617.5 1310 617.75 817 618 1157 618.25 726 618.5 1667 618.75 168 619 465 619.25 250 619.5 793 619.75 1574 620 497 620.25 1726 620.5 1172 620.75 1668 621 437 621.25 828 621.5 294 621.75 683 622 89 622.25 810 622.5 257 622.75 1740 623 -22 623.25 496 623.5 877 623.75 354 624 1601 624.25 1303 624.5 662 624.75 1275 625 93 625.25 1129 625.5 -274 625.75 584 626 -88 626.25 151 626.5 591 626.75 774 627 946 627.25 512 627.5 261 627.75 746 628 359 628.25 277 628.5 807 628.75 654 629 1440 629.25 480 629.5 798 629.75 202 630 1082 630.25 618 630.5 1424 630.75 1692 631 2265 631.25 -273 631.5 739 631.75 -708 632 525 632.25 749 632.5 900 632.75 341 633 -249 633.25 -42 633.5 1083 633.75 957 634 963 634.25 113 634.5 893 634.75 986 635 285 635.25 722 635.5 -48 635.75 379 636 -543 636.25 1006 636.5 840 636.75 52 637 420 637.25 1148 637.5 1748 637.75 1009 638 1555 638.25 1642 638.5 124 638.75 203 639 949 639.25 1811 639.5 -101 639.75 239 640 -371 640.25 108 640.5 1031 640.75 920 641 1693 641.25 1345 641.5 1093 641.75 1220 642 -128 642.25 -222 642.5 865 642.75 607 643 668 643.25 611 643.5 49 643.75 385 644 762 644.25 1858 644.5 1296 644.75 1934 645 -173 645.25 -88 645.5 1622 645.75 1371 646 771 646.25 1180 646.5 40 646.75 125 647 543 647.25 378 647.5 765 647.75 -373 648 -179 648.25 358 648.5 2200 648.75 925 649 866 649.25 -475 649.5 1152 649.75 580 650 1013 650.25 1236 650.5 -201 650.75 -581 651 831 651.25 1257 651.5 -175 651.75 922 652 96 652.25 465 652.5 -171 652.75 -75 653 871 653.25 2146 653.5 -882 653.75 315 654 -722 654.25 484 654.5 560 654.75 915 655 1866 655.25 -52 655.5 368 655.75 804 656 -185 656.25 1506 656.5 632 656.75 1041 657 191 657.25 1040 657.5 -259 657.75 1303 658 494 658.25 1348 658.5 -657 658.75 1217 659 1389 659.25 1192 659.5 300 659.75 274 660 1769 660.25 0 660.5 -526 660.75 1351 661 1476 661.25 -202 661.5 -708 661.75 439 662 981 662.25 -152 662.5 94 662.75 776 663 -33 663.25 459 663.5 238 663.75 835 664 742 664.25 311 664.5 293 664.75 723 665 933 665.25 423 665.5 144 665.75 177 666 -19 666.25 -96 666.5 786 666.75 1258 667 -805 667.25 1756 667.5 946 667.75 844 668 -153 668.25 480 668.5 808 668.75 7 669 1286 669.25 1288 669.5 -214 669.75 1565 670 903 670.25 359 670.5 1004 670.75 2081 671 13 671.25 -1087 671.5 1999 671.75 1197 672 -434 672.25 300 672.5 636 672.75 -1131 673 70 673.25 -349 673.5 1191 673.75 1862 674 1221 674.25 1284 674.5 1052 674.75 479 675 826 675.25 1680 675.5 356 675.75 70 676 475 676.25 248 676.5 901 676.75 120 677 -223 677.25 562 677.5 226 677.75 496 678 239 678.25 532 678.5 -661 678.75 511 679 199 679.25 1047 679.5 1038 679.75 298 680 597 680.25 203 680.5 1804 680.75 436 681 848 681.25 1299 681.5 1169 681.75 466 682 816 682.25 409 682.5 -326 682.75 -126 683 1141 683.25 -42 683.5 -344 683.75 -126 684 266 684.25 936 684.5 1378 684.75 386 685 342 685.25 413 685.5 717 685.75 -607 686 13 686.25 172 686.5 -182 686.75 -146 687 297 687.25 601 687.5 700 687.75 1672 688 897 688.25 53 688.5 253 688.75 229 689 824 689.25 462 689.5 1455 689.75 -69 690 602 690.25 403 690.5 1220 690.75 1385 691 868 691.25 997 691.5 180 691.75 50 692 606 692.25 123 692.5 417 692.75 760 693 1557 693.25 2358 693.5 527 693.75 566 694 546 694.25 -13 694.5 945 694.75 2209 695 741 695.25 975 695.5 510 695.75 -95 696 -29 696.25 1389 696.5 -203 696.75 -995 697 562 697.25 -152 697.5 877 697.75 954 698 272 698.25 1349 698.5 1284 698.75 -935 699 -912 699.25 812 699.5 -904 699.75 1111 700 -1394