# Optical absorption spectrum of N,N'-Difluoroboryl-1,9-dimethyl-5-phenydipyrrin in toluene # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by R. W. Wagner in 1994 using a Cary 3. # The absorption values were collected using a spectral bandwidth of 1.0 nm, a signal averaging time of 0.133 sec, a data interval of 0.25 nm, and a scan rate of 112.5 nm/min. # # These measurements were scaled to make the molar extinction coefficient match # the value of 54000 cm-1/M at 503.0 nm. These values were # then interpolated to report extinction coefficients at regular 1nm intervals # # The reported molar extinction coefficient is from # Wagner, R. W. and J. S. Lindsey (1996) Boron-dipyrromethene dyes for incorporation in synthetic multi-pigment light-harvesting arrays. Pure Appl. Chem. 68, 1373-1380. # ##Wavelength (nm) Molar Extinction (cm-1/M) 349.75 11674 350 11631 350.25 11615 350.5 11617 350.75 11438 351 11330 351.25 11172 351.5 11244 351.75 11085 352 11167 352.25 11325 352.5 11087 352.75 11094 353 11011 353.25 10860 353.5 10850 353.75 10877 354 10764 354.25 10593 354.5 10627 354.75 10488 355 10486 355.25 10395 355.5 10277 355.75 10258 356 10141 356.25 9940 356.5 9991 356.75 10078 357 9793 357.25 9722 357.5 9683 357.75 9557 358 9638 358.25 9625 358.5 9372 358.75 9559 359 9300 359.25 9279 359.5 9171 359.75 9048 360 8925 360.25 8947 360.5 8787 360.75 8848 361 8796 361.25 8516 361.5 8592 361.75 8575 362 8573 362.25 8383 362.5 8420 362.75 8183 363 8114 363.25 8099 363.5 8106 363.75 8007 364 7785 364.25 7755 364.5 7803 364.75 7759 365 7576 365.25 7654 365.5 7645 365.75 7466 366 7338 366.25 7277 366.5 7215 366.75 7217 367 7090 367.25 7012 367.5 7069 367.75 6941 368 6928 368.25 6869 368.5 6773 368.75 6776 369 6630 369.25 6661 369.5 6621 369.75 6473 370 6465 370.25 6268 370.5 6163 370.75 6149 371 6033 371.25 6144 371.5 6058 371.75 5991 372 6032 372.25 5882 372.5 5712 372.75 5836 373 5729 373.25 5699 373.5 5489 373.75 5603 374 5520 374.25 5594 374.5 5440 374.75 5329 375 5405 375.25 5363 375.5 5373 375.75 5366 376 5133 376.25 5275 376.5 5173 376.75 5138 377 5092 377.25 5027 377.5 5217 377.75 4891 378 5004 378.25 4887 378.5 4933 378.75 4768 379 4850 379.25 4775 379.5 4544 379.75 4676 380 4747 380.25 4714 380.5 4551 380.75 4652 381 4537 381.25 4488 381.5 4489 381.75 4507 382 4490 382.25 4535 382.5 4472 382.75 4318 383 4317 383.25 4324 383.5 4358 383.75 4383 384 4231 384.25 4215 384.5 4252 384.75 4184 385 4033 385.25 4023 385.5 4120 385.75 3962 386 3998 386.25 3940 386.5 3956 386.75 4025 387 4041 387.25 3940 387.5 3836 387.75 3909 388 3792 388.25 3719 388.5 3722 388.75 3725 389 3736 389.25 3661 389.5 3624 389.75 3521 390 3429 390.25 3529 390.5 3475 390.75 3446 391 3308 391.25 3231 391.5 3349 391.75 3277 392 3188 392.25 3223 392.5 3163 392.75 3148 393 3012 393.25 3020 393.5 2953 393.75 2947 394 2863 394.25 2800 394.5 2816 394.75 2770 395 2662 395.25 2487 395.5 2706 395.75 2530 396 2371 396.25 2371 396.5 2366 396.75 2293 397 2269 397.25 2316 397.5 2321 397.75 2150 398 2092 398.25 2122 398.5 2177 398.75 1995 399 1928 399.25 1993 399.5 2034 399.75 1723 400 1910 400.25 1774 400.5 1797 400.75 1701 401 1657 401.25 1700 401.5 1528 401.75 1700 402 1655 402.25 1605 402.5 1523 402.75 1542 403 1541 403.25 1542 403.5 1527 403.75 1475 404 1383 404.25 1342 404.5 1251 404.75 1276 405 1283 405.25 1201 405.5 1322 405.75 1181 406 1243 406.25 1103 406.5 1199 406.75 1179 407 1125 407.25 1152 407.5 1139 407.75 959 408 1076 408.25 1150 408.5 1061 408.75 987 409 1080 409.25 975 409.5 1006 409.75 926 410 964 410.25 927 410.5 1095 410.75 1021 411 983 411.25 1003 411.5 1000 411.75 944 412 965 412.25 943 412.5 927 412.75 979 413 933 413.25 804 413.5 871 413.75 928 414 908 414.25 940 414.5 888 414.75 876 415 998 415.25 912 415.5 822 415.75 1012 416 870 416.25 861 416.5 927 416.75 1010 417 978 417.25 989 417.5 913 417.75 971 418 944 418.25 1017 418.5 979 418.75 957 419 971 419.25 952 419.5 932 419.75 955 420 965 420.25 1009 420.5 1024 420.75 1091 421 1006 421.25 1083 421.5 1078 421.75 1119 422 1080 422.25 1160 422.5 1080 422.75 1152 423 1127 423.25 1199 423.5 1147 423.75 1128 424 1100 424.25 1171 424.5 1242 424.75 1281 425 1257 425.25 1297 425.5 1232 425.75 1327 426 1386 426.25 1233 426.5 1320 426.75 1275 427 1282 427.25 1303 427.5 1376 427.75 1393 428 1357 428.25 1441 428.5 1388 428.75 1393 429 1451 429.25 1418 429.5 1437 429.75 1550 430 1481 430.25 1516 430.5 1588 430.75 1561 431 1492 431.25 1651 431.5 1598 431.75 1625 432 1684 432.25 1788 432.5 1661 432.75 1763 433 1776 433.25 1687 433.5 1811 433.75 1787 434 1858 434.25 1944 434.5 1840 434.75 1992 435 1925 435.25 1993 435.5 2041 435.75 2003 436 2084 436.25 2142 436.5 2213 436.75 2183 437 2165 437.25 2172 437.5 2316 437.75 2331 438 2391 438.25 2419 438.5 2332 438.75 2470 439 2549 439.25 2487 439.5 2641 439.75 2590 440 2673 440.25 2681 440.5 2698 440.75 2759 441 2791 441.25 2900 441.5 2881 441.75 2930 442 3005 442.25 2979 442.5 3081 442.75 3137 443 3139 443.25 3135 443.5 3282 443.75 3350 444 3378 444.25 3346 444.5 3347 444.75 3472 445 3552 445.25 3550 445.5 3610 445.75 3719 446 3721 446.25 3702 446.5 3834 446.75 3847 447 3853 447.25 3944 447.5 4097 447.75 4071 448 4136 448.25 4233 448.5 4256 448.75 4336 449 4400 449.25 4520 449.5 4435 449.75 4607 450 4704 450.25 4687 450.5 4786 450.75 4776 451 4958 451.25 4962 451.5 4949 451.75 5080 452 5210 452.25 5179 452.5 5204 452.75 5393 453 5407 453.25 5470 453.5 5492 453.75 5581 454 5642 454.25 5757 454.5 5791 454.75 5818 455 5945 455.25 5958 455.5 5993 455.75 6131 456 6241 456.25 6209 456.5 6376 456.75 6397 457 6577 457.25 6590 457.5 6718 457.75 6823 458 6922 458.25 6997 458.5 7160 458.75 7248 459 7340 459.25 7426 459.5 7567 459.75 7675 460 7788 460.25 7862 460.5 8074 460.75 8187 461 8328 461.25 8436 461.5 8653 461.75 8663 462 8901 462.25 8969 462.5 9195 462.75 9361 463 9437 463.25 9623 463.5 9736 463.75 9959 464 10157 464.25 10359 464.5 10469 464.75 10698 465 10838 465.25 11067 465.5 11177 465.75 11336 466 11547 466.25 11781 466.5 11899 466.75 12168 467 12341 467.25 12457 467.5 12825 467.75 12963 468 13161 468.25 13371 468.5 13635 468.75 13829 469 14067 469.25 14210 469.5 14405 469.75 14654 470 14933 470.25 15101 470.5 15336 470.75 15543 471 15681 471.25 15975 471.5 16138 471.75 16314 472 16521 472.25 16868 472.5 16974 472.75 17256 473 17442 473.25 17593 473.5 17740 473.75 17953 474 18178 474.25 18337 474.5 18508 474.75 18772 475 18939 475.25 19163 475.5 19450 475.75 19599 476 19863 476.25 19959 476.5 20249 476.75 20354 477 20555 477.25 20675 477.5 20785 477.75 20959 478 21110 478.25 21212 478.5 21333 478.75 21371 479 21492 479.25 21605 479.5 21804 479.75 21942 480 21982 480.25 22132 480.5 22175 480.75 22391 481 22485 481.25 22505 481.5 22543 481.75 22710 482 22821 482.25 22900 482.5 23054 482.75 23129 483 23236 483.25 23373 483.5 23449 483.75 23586 484 23720 484.25 23869 484.5 23992 484.75 24096 485 24206 485.25 24431 485.5 24485 485.75 24705 486 24868 486.25 25038 486.5 25314 486.75 25430 487 25687 487.25 25842 487.5 26092 487.75 26343 488 26553 488.25 26873 488.5 27220 488.75 27430 489 27796 489.25 28099 489.5 28505 489.75 28752 490 29327 490.25 29658 490.5 30103 490.75 30375 491 30940 491.25 31313 491.5 31873 491.75 32323 492 33008 492.25 33305 492.5 33958 492.75 34570 493 35049 493.25 35684 493.5 36267 493.75 36717 494 37353 494.25 37938 494.5 38242 494.75 38520 495 38984 495.25 39579 495.5 40317 495.75 40847 496 41517 496.25 42145 496.5 42802 496.75 43544 497 44038 497.25 44776 497.5 45443 497.75 45939 498 46661 498.25 47016 498.5 47713 498.75 48414 499 49027 499.25 49276 499.5 49781 499.75 50473 500 50954 500.25 51377 500.5 51629 500.75 52174 501 52523 501.25 52835 501.5 53095 501.75 53141 502 53451 502.25 53588 502.5 53684 502.75 54020 503 54000 503.25 53737 503.5 53952 503.75 53738 504 53723 504.25 53608 504.5 53291 504.75 53273 505 53079 505.25 52774 505.5 52244 505.75 51890 506 51559 506.25 51054 506.5 50493 506.75 50153 507 49640 507.25 48908 507.5 48353 507.75 47737 508 46968 508.25 46448 508.5 45759 508.75 45047 509 44277 509.25 43496 509.5 42832 509.75 41848 510 40911 510.25 40240 510.5 39341 510.75 38403 511 37650 511.25 36746 511.5 36107 511.75 35050 512 34094 512.25 33328 512.5 32461 512.75 31569 513 30667 513.25 30047 513.5 29161 513.75 28251 514 27439 514.25 26616 514.5 25980 514.75 25084 515 24257 515.25 23290 515.5 22323 515.75 21414 516 20607 516.25 19747 516.5 19128 516.75 18330 517 17847 517.25 17215 517.5 16610 517.75 16009 518 15490 518.25 14847 518.5 14480 518.75 13882 519 13344 519.25 12885 519.5 12480 519.75 11999 520 11556 520.25 11169 520.5 10707 520.75 10199 521 9845 521.25 9521 521.5 9172 521.75 8892 522 8457 522.25 8101 522.5 7800 522.75 7475 523 7312 523.25 6878 523.5 6668 523.75 6389 524 6190 524.25 5899 524.5 5608 524.75 5432 525 5248 525.25 5033 525.5 4795 525.75 4632 526 4359 526.25 4151 526.5 4044 526.75 3778 527 3697 527.25 3564 527.5 3435 527.75 3330 528 3151 528.25 2996 528.5 2930 528.75 2741 529 2553 529.25 2467 529.5 2433 529.75 2355 530 2240 530.25 2143 530.5 2061 530.75 1992 531 1881 531.25 1766 531.5 1758 531.75 1669 532 1570 532.25 1533 532.5 1480 532.75 1403 533 1349 533.25 1288 533.5 1208 533.75 1139 534 1122 534.25 1079 534.5 1103 534.75 1043 535 950 535.25 977 535.5 916 535.75 874 536 777 536.25 829 536.5 800 536.75 718 537 739 537.25 711 537.5 674 537.75 631 538 640 538.25 567 538.5 550 538.75 541 539 575 539.25 523 539.5 525 539.75 435 540 410 540.25 389 540.5 445 540.75 371 541 421 541.25 315 541.5 330 541.75 310 542 270 542.25 311 542.5 290 542.75 345 543 306 543.25 243 543.5 219 543.75 268 544 197 544.25 169 544.5 283 544.75 212 545 190 545.25 247 545.5 225 545.75 172 546 148 546.25 180 546.5 175 546.75 156 547 165 547.25 156 547.5 189 547.75 129 548 163 548.25 108 548.5 139 548.75 72 549 86 549.25 112 549.5 108 549.75 72 550 125 550.25 149 550.5 77 550.75 117 551 134 551.25 81 551.5 44 551.75 45 552 62 552.25 49 552.5 87 552.75 58 553 30 553.25 90 553.5 86 553.75 31 554 120 554.25 76 554.5 15 554.75 56 555 71 555.25 83 555.5 95 555.75 89 556 47 556.25 19 556.5 -1 556.75 23 557 102 557.25 63 557.5 43 557.75 65 558 41 558.25 36 558.5 20 558.75 18 559 52 559.25 114 559.5 23 559.75 42 560 0 560.25 31 560.5 57 560.75 125 561 10 561.25 3 561.5 99 561.75 42 562 57 562.25 23 562.5 47 562.75 19 563 61 563.25 62 563.5 56 563.75 26 564 41 564.25 75 564.5 50 564.75 36 565 55 565.25 35 565.5 4 565.75 36 566 7 566.25 66 566.5 32 566.75 10 567 38 567.25 -38 567.5 37 567.75 -31 568 1 568.25 1 568.5 44 568.75 6 569 34 569.25 -16 569.5 -11 569.75 64 570 46 570.25 47 570.5 63 570.75 30 571 -18 571.25 -35 571.5 11 571.75 1 572 75 572.25 -55 572.5 71 572.75 62 573 -13 573.25 -21 573.5 69 573.75 21 574 49 574.25 -5 574.5 34 574.75 -19 575 59 575.25 65 575.5 -22 575.75 20 576 -32 576.25 10 576.5 33 576.75 46 577 -8 577.25 65 577.5 -22 577.75 65 578 64 578.25 0 578.5 15 578.75 15 579 91 579.25 36 579.5 -29 579.75 14 580 102 580.25 95 580.5 15 580.75 72 581 9 581.25 89 581.5 -5 581.75 31 582 30 582.25 -4 582.5 87 582.75 -27 583 13 583.25 64 583.5 76 583.75 -31 584 60 584.25 90 584.5 103 584.75 4 585 34 585.25 59 585.5 42 585.75 45 586 42 586.25 -1 586.5 -13 586.75 14 587 20 587.25 23 587.5 8 587.75 22 588 30 588.25 43 588.5 4 588.75 52 589 70 589.25 92 589.5 27 589.75 50 590 95 590.25 -24 590.5 66 590.75 69 591 41 591.25 85 591.5 63 591.75 46 592 45 592.25 42 592.5 72 592.75 38 593 67 593.25 51 593.5 95 593.75 -13 594 9 594.25 88 594.5 17 594.75 23 595 21 595.25 44 595.5 12 595.75 39 596 63 596.25 52 596.5 85 596.75 26 597 25 597.25 13 597.5 78 597.75 6 598 18 598.25 83 598.5 -21 598.75 61 599 59 599.25 39 599.5 76 599.75 1 600 61 600.25 -27 600.5 49 600.75 19 601 24 601.25 80 601.5 40 601.75 -28 602 24 602.25 52 602.5 58 602.75 121 603 9 603.25 55 603.5 20 603.75 81 604 -9 604.25 -6 604.5 10 604.75 22 605 2 605.25 42 605.5 -35 605.75 53 606 111 606.25 -1 606.5 85 606.75 -9 607 9 607.25 50 607.5 45 607.75 61 608 -7 608.25 121 608.5 0 608.75 95 609 28 609.25 41 609.5 47 609.75 -108 610 26 610.25 1 610.5 3 610.75 70 611 74 611.25 5 611.5 -28 611.75 50 612 56 612.25 120 612.5 -12 612.75 64 613 67 613.25 136 613.5 90 613.75 -57 614 -11 614.25 38 614.5 0 614.75 115 615 40 615.25 96 615.5 -13 615.75 -22 616 -13 616.25 30 616.5 40 616.75 16 617 50 617.25 4 617.5 45 617.75 3 618 -24 618.25 32 618.5 60 618.75 13 619 121 619.25 24 619.5 66 619.75 28 620 69 620.25 55 620.5 15 620.75 49 621 -12 621.25 108 621.5 24 621.75 25 622 -26 622.25 53 622.5 19 622.75 -21 623 -9 623.25 2 623.5 93 623.75 118 624 -14 624.25 5 624.5 57 624.75 35 625 29 625.25 43 625.5 10 625.75 16 626 -10 626.25 -28 626.5 -18 626.75 9 627 39 627.25 -51 627.5 29 627.75 11 628 16 628.25 22 628.5 -33 628.75 31 629 5 629.25 60 629.5 17 629.75 11 630 -16 630.25 -1 630.5 13 630.75 53 631 7 631.25 59 631.5 -26 631.75 -29 632 83 632.25 167 632.5 -32 632.75 22 633 -16 633.25 49 633.5 64 633.75 20 634 0 634.25 8 634.5 -22 634.75 38 635 -10 635.25 23 635.5 35 635.75 44 636 0 636.25 0 636.5 19 636.75 71 637 75 637.25 63 637.5 51 637.75 20 638 -44 638.25 -71 638.5 -27 638.75 94 639 118 639.25 -5 639.5 0 639.75 -47 640 16 640.25 88 640.5 -10 640.75 91 641 16 641.25 53 641.5 -19 641.75 150 642 50 642.25 117 642.5 36 642.75 32 643 12 643.25 12 643.5 -23 643.75 -30 644 55 644.25 78 644.5 16 644.75 35 645 21 645.25 25 645.5 49 645.75 33 646 81 646.25 -41 646.5 103 646.75 1 647 -8 647.25 -24 647.5 60 647.75 31 648 9 648.25 36 648.5 -2 648.75 84 649 3 649.25 80 649.5 52 649.75 -75 650 54 650.25 65 650.5 26 650.75 9 651 35 651.25 -23 651.5 -3 651.75 51 652 40 652.25 -12 652.5 92 652.75 56 653 66 653.25 97 653.5 138 653.75 69 654 -66 654.25 41 654.5 53 654.75 48 655 -33 655.25 124 655.5 19 655.75 27 656 -26 656.25 66 656.5 108 656.75 -5 657 21 657.25 1 657.5 124 657.75 130 658 127 658.25 31 658.5 29 658.75 60 659 23 659.25 134 659.5 -30 659.75 32 660 74 660.25 -37 660.5 146 660.75 118 661 22 661.25 16 661.5 19 661.75 11 662 28 662.25 51 662.5 11 662.75 47 663 75 663.25 92 663.5 14 663.75 39 664 19 664.25 80 664.5 -18 664.75 62 665 114 665.25 77 665.5 -126 665.75 -12 666 27 666.25 78 666.5 27 666.75 42 667 -58 667.25 29 667.5 -20 667.75 -63 668 13 668.25 -42 668.5 115 668.75 -20 669 113 669.25 37 669.5 25 669.75 -70 670 8 670.25 25 670.5 26 670.75 -7 671 50 671.25 90 671.5 26 671.75 45 672 63 672.25 -23 672.5 -22 672.75 -64 673 46 673.25 5 673.5 -57 673.75 51 674 22 674.25 35 674.5 74 674.75 59 675 66 675.25 89 675.5 22 675.75 46 676 56 676.25 -30 676.5 52 676.75 41 677 37 677.25 17 677.5 -12 677.75 88 678 80 678.25 -21 678.5 -47 678.75 54 679 81 679.25 60 679.5 77 679.75 37 680 43 680.25 116 680.5 -73 680.75 11 681 63 681.25 -18 681.5 56 681.75 69 682 13 682.25 59 682.5 17 682.75 88 683 -16 683.25 -17 683.5 42 683.75 44 684 44 684.25 4 684.5 65 684.75 0 685 -101 685.25 6 685.5 5 685.75 39 686 2 686.25 -11 686.5 54 686.75 33 687 46 687.25 -64 687.5 31 687.75 44 688 1 688.25 27 688.5 -4 688.75 65 689 103 689.25 -5 689.5 -32 689.75 -22 690 85 690.25 -27 690.5 20 690.75 72 691 38 691.25 79 691.5 -89 691.75 59 692 38 692.25 50 692.5 24 692.75 105 693 48 693.25 -1 693.5 0 693.75 107 694 38 694.25 38 694.5 -64 694.75 -36 695 30 695.25 -8 695.5 146 695.75 26 696 6 696.25 79 696.5 45 696.75 -4 697 74 697.25 112 697.5 107 697.75 51 698 -4 698.25 -55 698.5 16 698.75 22 699 38 699.25 -34 699.5 66 699.75 -33 700 -83