# Emission spectrum of in chloroform + HCl # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by on on 12-11-1997 # using a Spex FluoroMax. The excitation and emission monochromators were set at 1 mm, giving a spectral bandwidth of 4.25 nm. The data interval was 0.5 nm and the integration time was 2.0 sec. Samples were prepared in 1cm pathlength quartz cells with absorbance less than 0.1 at the excitation and all emission wavelengths to uniformly illuminate across the sample, and to avoid the inner-filter effect. The dark counts were subtracted and the spectra were corrected for wavelength-dependent instrument sensitivity. # ##Wavelength (nm) Emission (AU) 600 25079 601 25752 602 24912 603 24573 604 25184 605 24595 606 24585 607 24362 608 24963 609 24570 610 24527 611 24809 612 24865 613 24295 614 25201 615 25463 616 25627 617 26056 618 26528 619 27212 620 27393 621 28365 622 29341 623 29315 624 31218 625 33170 626 35052 627 36086 628 39035 629 42236 630 47481 631 51577 632 58641 633 65980 634 76320 635 88841 636 106194 637 125577 638 148132 639 174385 640 209927 641 250010 642 302395 643 357948 644 426797 645 502351 646 600331 647 699394 648 827079 649 969092 650 1152619 651 1338150 652 1561855 653 1792726 654 2057573 655 2317855 656 2617594 657 2935788 658 3283137 659 3623936 660 4023792 661 4403736 662 4832270 663 5229557 664 5668477 665 6076073 666 6541141 667 6940092 668 7363651 669 7787142 670 8192338 671 8601820 672 9021877 673 9394784 674 9773752 675 10071050 676 10410320 677 10685690 678 10928260 679 11132760 680 11328070 681 11501160 682 11644100 683 11750890 684 11825900 685 11868710 686 11916960 687 11935630 688 11888400 689 11844830 690 11757170 691 11691680 692 11615090 693 11478790 694 11325780 695 11170020 696 10992050 697 10828180 698 10585270 699 10398480 700 10168680 701 9951083 702 9731850 703 9525182 704 9300123 705 9088446 706 8856920 707 8615846 708 8374742 709 8148424 710 7910635 711 7709501 712 7489989 713 7284253 714 7070563 715 6902353 716 6708934 717 6535053 718 6361083 719 6189842 720 6007518 721 5864582 722 5691732 723 5569220 724 5433474 725 5316481 726 5171945 727 5116875 728 5003058 729 4898812 730 4815781 731 4725970 732 4647696 733 4576983 734 4510465 735 4435450 736 4386858 737 4337701 738 4256923 739 4243722 740 4184185 741 4124733 742 4087452 743 4053836 744 4008213 745 3954273 746 3894571 747 3841087 748 3798078 749 3751179 750 3712561 751 3661064 752 3604980 753 3565648 754 3504944 755 3452727 756 3402300 757 3328783 758 3273069 759 3214960 760 3158231 761 3118541 762 3039447 763 2995363 764 2926024 765 2872478 766 2815990 767 2750516 768 2698440 769 2618989 770 2552393 771 2508217 772 2439566 773 2379460 774 2315204 775 2274063 776 2214824 777 2148192 778 2081501 779 2032778 780 1964769 781 1913297 782 1849160 783 1817622 784 1739514 785 1685595 786 1640878 787 1589131 788 1526343 789 1484939 790 1434547 791 1393568 792 1355129 793 1308877 794 1254626 795 1219348 796 1167246 797 1139626 798 1099400 799 1070621 800 1025962