# Optical absorption spectrum of Benzoquinone in hexane # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by J. Li on 12-11-1997 using a Cary 3. # The absorption values were collected using a spectral bandwidth of 1.0 nm, a signal averaging time of 0.133 sec, a data interval of 0.25 nm, and a scan rate of 112.5 nm/min. # # These measurements were scaled to make the molar extinction coefficient match # the value of 24300 cm-1/M at 239.8 nm. These values were # then interpolated to report extinction coefficients at regular 1nm intervals # # The reported molar extinction coefficient is from # Braude, E. A. (1945) Studies in light absorption. Part I. p-Benzoquinones. J. Chem. Soc. 45, 490-497. # ##Wavelength (nm) Molar Extinction (cm-1/M) 199.75 2258 200 2194 200.25 2894 200.5 2329 200.75 2536 201 2159 201.25 2056 201.5 2483 201.75 2365 202 2382 202.25 2557 202.5 2358 202.75 2488 203 2842 203.25 2912 203.5 2333 203.75 2736 204 2576 204.25 2538 204.5 2550 204.75 2647 205 2707 205.25 2899 205.5 2706 205.75 2877 206 2765 206.25 3048 206.5 2762 206.75 2927 207 3177 207.25 3191 207.5 3346 207.75 2976 208 3177 208.25 3233 208.5 3220 208.75 3457 209 3415 209.25 3521 209.5 3555 209.75 3649 210 3681 210.25 3818 210.5 3758 210.75 3679 211 3935 211.25 4010 211.5 4012 211.75 4092 212 4191 212.25 4129 212.5 4299 212.75 4428 213 4476 213.25 4449 213.5 4694 213.75 4753 214 4796 214.25 5056 214.5 5165 214.75 5335 215 5373 215.25 5548 215.5 5507 215.75 5575 216 5689 216.25 5776 216.5 5924 216.75 5982 217 6061 217.25 6290 217.5 6359 217.75 6558 218 6648 218.25 6828 218.5 7050 218.75 7119 219 7485 219.25 7604 219.5 7639 219.75 7867 220 7944 220.25 8191 220.5 8503 220.75 8601 221 8609 221.25 8938 221.5 9319 221.75 9423 222 9459 222.25 9856 222.5 10029 222.75 10119 223 10353 223.25 10584 223.5 10847 223.75 10972 224 11057 224.25 11575 224.5 11564 224.75 11678 225 11915 225.25 12323 225.5 12519 225.75 12579 226 12899 226.25 13117 226.5 13319 226.75 13668 227 13811 227.25 14102 227.5 14249 227.75 14561 228 14911 228.25 15028 228.5 15215 228.75 15609 229 15774 229.25 15955 229.5 16323 229.75 16461 230 16789 230.25 17148 230.5 17352 230.75 17519 231 17914 231.25 18005 231.5 18068 231.75 18343 232 18727 232.25 18827 232.5 19094 232.75 19306 233 19483 233.25 19482 233.5 19820 233.75 20174 234 20328 234.25 20539 234.5 20594 234.75 20690 235 21361 235.25 21474 235.5 21691 235.75 21967 236 22056 236.25 22327 236.5 22291 236.75 22649 237 22756 237.25 22834 237.5 23467 237.75 23240 238 23523 238.25 23754 238.5 23822 238.75 23791 239 23850 239.25 23890 239.5 24297 239.75 24334 240 24161 240.25 24253 240.5 24165 240.75 23911 241 24022 241.25 23926 241.5 23519 241.75 23975 242 23280 242.25 23463 242.5 23359 242.75 23176 243 22953 243.25 22662 243.5 22774 243.75 22184 244 22154 244.25 22169 244.5 22008 244.75 21785 245 21735 245.25 21321 245.5 21134 245.75 21091 246 20992 246.25 20789 246.5 20291 246.75 20630 247 20341 247.25 20133 247.5 19997 247.75 19805 248 19727 248.25 19538 248.5 19130 248.75 18874 249 18652 249.25 18230 249.5 17942 249.75 17419 250 17178 250.25 16551 250.5 16181 250.75 15717 251 14920 251.25 14372 251.5 13723 251.75 13222 252 12497 252.25 11913 252.5 11261 252.75 10609 253 10021 253.25 9379 253.5 8948 253.75 8376 254 7804 254.25 7205 254.5 6711 254.75 6326 255 6031 255.25 5771 255.5 5410 255.75 5164 256 4839 256.25 4382 256.5 4160 256.75 3817 257 3436 257.25 3225 257.5 2970 257.75 2796 258 2575 258.25 2282 258.5 2086 258.75 1849 259 1702 259.25 1525 259.5 1569 259.75 1392 260 1322 260.25 1181 260.5 1124 260.75 1091 261 922 261.25 882 261.5 839 261.75 838 262 802 262.25 847 262.5 763 262.75 649 263 620 263.25 594 263.5 604 263.75 521 264 630 264.25 499 264.5 578 264.75 499 265 442 265.25 466 265.5 437 265.75 387 266 510 266.25 532 266.5 392 266.75 412 267 398 267.25 391 267.5 487 267.75 483 268 439 268.25 396 268.5 350 268.75 340 269 353 269.25 465 269.5 443 269.75 412 270 485 270.25 494 270.5 394 270.75 375 271 337 271.25 466 271.5 423 271.75 391 272 393 272.25 417 272.5 491 272.75 406 273 414 273.25 434 273.5 474 273.75 483 274 375 274.25 375 274.5 448 274.75 406 275 417 275.25 447 275.5 442 275.75 375 276 424 276.25 336 276.5 448 276.75 380 277 440 277.25 377 277.5 453 277.75 418 278 457 278.25 329 278.5 331 278.75 298 279 391 279.25 423 279.5 388 279.75 393 280 355 280.25 433 280.5 367 280.75 397 281 409 281.25 415 281.5 420 281.75 309 282 380 282.25 477 282.5 464 282.75 468 283 417 283.25 329 283.5 316 283.75 334 284 402 284.25 377 284.5 382 284.75 395 285 410 285.25 464 285.5 285 285.75 424 286 405 286.25 350 286.5 329 286.75 371 287 424 287.25 339 287.5 442 287.75 267 288 390 288.25 360 288.5 383 288.75 346 289 466 289.25 266 289.5 380 289.75 326 290 272 290.25 261 290.5 348 290.75 289 291 303 291.25 291 291.5 277 291.75 322 292 381 292.25 250 292.5 291 292.75 386 293 228 293.25 293 293.5 281 293.75 278 294 309 294.25 311 294.5 335 294.75 301 295 283 295.25 189 295.5 275 295.75 295 296 279 296.25 277 296.5 300 296.75 185 297 211 297.25 290 297.5 244 297.75 235 298 236 298.25 262 298.5 221 298.75 235 299 192 299.25 206 299.5 223 299.75 240 300 161 300.25 180 300.5 177 300.75 186 301 217 301.25 199 301.5 199 301.75 213 302 184 302.25 165 302.5 141 302.75 220 303 120 303.25 196 303.5 200 303.75 173 304 207 304.25 110 304.5 141 304.75 143 305 217 305.25 135 305.5 175 305.75 121 306 75 306.25 108 306.5 105 306.75 80 307 117 307.25 83 307.5 145 307.75 182 308 100 308.25 14 308.5 29 308.75 139 309 35 309.25 -8 309.5 78 309.75 8 310 72 310.25 75 310.5 51 310.75 -12 311 48 311.25 136 311.5 95 311.75 33 312 79 312.25 -28 312.5 83 312.75 82 313 124 313.25 106 313.5 18 313.75 7 314 96 314.25 137 314.5 13 314.75 -77 315 49 315.25 58 315.5 74 315.75 17 316 -7 316.25 54 316.5 -36 316.75 -130 317 85 317.25 66 317.5 -57 317.75 6 318 46 318.25 9 318.5 -1 318.75 -28 319 -43 319.25 26 319.5 75 319.75 -49 320 26 320.25 33 320.5 85 320.75 43 321 -41 321.25 -3 321.5 -99 321.75 -112 322 11 322.25 -39 322.5 20 322.75 -95 323 52 323.25 50 323.5 3 323.75 88 324 45 324.25 29 324.5 -120 324.75 4 325 -63 325.25 -65 325.5 -17 325.75 38 326 -51 326.25 -96 326.5 -74 326.75 71 327 121 327.25 148 327.5 -27 327.75 76 328 -105 328.25 26 328.5 -45 328.75 36 329 25 329.25 -140 329.5 -74 329.75 116 330 -171 330.25 34 330.5 29 330.75 83 331 -16 331.25 -63 331.5 -49 331.75 47 332 53 332.25 -7 332.5 15 332.75 58 333 40 333.25 -3 333.5 57 333.75 -5 334 -26 334.25 8 334.5 -26 334.75 48 335 -42 335.25 -139 335.5 -209 335.75 25 336 -75 336.25 20 336.5 -71 336.75 17 337 -125 337.25 13 337.5 -91 337.75 -20 338 -21 338.25 -62 338.5 -54 338.75 -80 339 65 339.25 8 339.5 -51 339.75 -23 340 2 340.25 -45 340.5 -107 340.75 56 341 -35 341.25 -30 341.5 38 341.75 -2 342 83 342.25 -19 342.5 -98 342.75 39 343 -48 343.25 34 343.5 -2 343.75 162 344 50 344.25 69 344.5 -10 344.75 -48 345 -52 345.25 -84 345.5 -84 345.75 89 346 17 346.25 24 346.5 -6 346.75 -49 347 -24 347.25 38 347.5 -153 347.75 0 348 73 348.25 -123 348.5 -24 348.75 -80 349 66 349.25 -60 349.5 -177 349.75 -9 350 -5 350.25 -59 350.5 57 350.75 -33 351 -22 351.25 38 351.5 41 351.75 21 352 5 352.25 56 352.5 -16 352.75 11 353 -60 353.25 16 353.5 39 353.75 -52 354 8 354.25 8 354.5 -38 354.75 -23 355 -7 355.25 9 355.5 -12 355.75 -45 356 47 356.25 26 356.5 23 356.75 80 357 37 357.25 -13 357.5 -27 357.75 -15 358 -86 358.25 -71 358.5 -7 358.75 -47 359 -14 359.25 -19 359.5 -12 359.75 -4 360 -75 360.25 -33 360.5 -38 360.75 -11 361 -22 361.25 10 361.5 0 361.75 -22 362 -25 362.25 49 362.5 33 362.75 0 363 48 363.25 -6 363.5 -69 363.75 -48 364 2 364.25 15 364.5 33 364.75 -65 365 -40 365.25 -45 365.5 -16 365.75 -35 366 -32 366.25 27 366.5 -4 366.75 -49 367 -17 367.25 -5 367.5 -14 367.75 32 368 -52 368.25 20 368.5 -9 368.75 30 369 64 369.25 -1 369.5 -40 369.75 8 370 -81 370.25 0 370.5 11 370.75 15 371 24 371.25 -44 371.5 -8 371.75 26 372 3 372.25 -64 372.5 -4 372.75 -48 373 28 373.25 17 373.5 -30 373.75 13 374 -44 374.25 -31 374.5 -33 374.75 10 375 -32 375.25 -32 375.5 -1 375.75 24 376 -19 376.25 40 376.5 -22 376.75 15 377 34 377.25 40 377.5 43 377.75 16 378 29 378.25 2 378.5 -60 378.75 -62 379 -61 379.25 -29 379.5 -14 379.75 -44 380 6 380.25 -20 380.5 50 380.75 3 381 23 381.25 29 381.5 31 381.75 -25 382 12 382.25 -13 382.5 77 382.75 4 383 9 383.25 56 383.5 -41 383.75 -1 384 1 384.25 -2 384.5 8 384.75 11 385 -24 385.25 14 385.5 2 385.75 36 386 -4 386.25 -28 386.5 -1 386.75 -18 387 29 387.25 38 387.5 49 387.75 27 388 52 388.25 -10 388.5 -67 388.75 8 389 7 389.25 -32 389.5 -1 389.75 -9 390 4 390.25 9 390.5 -35 390.75 -30 391 -5 391.25 28 391.5 -23 391.75 12 392 20 392.25 11 392.5 -16 392.75 43 393 6 393.25 25 393.5 -6 393.75 -13 394 34 394.25 -10 394.5 -2 394.75 8 395 13 395.25 -77 395.5 6 395.75 -17 396 -2 396.25 24 396.5 -9 396.75 -4 397 -2 397.25 -23 397.5 26 397.75 17 398 -49 398.25 2 398.5 6 398.75 21 399 23 399.25 -39 399.5 11 399.75 -36 400 55 400.25 -14 400.5 -21 400.75 -19 401 9 401.25 6 401.5 -52 401.75 0 402 23 402.25 17 402.5 13 402.75 15 403 17 403.25 28 403.5 -39 403.75 28 404 -11 404.25 -4 404.5 -1 404.75 9 405 14 405.25 10 405.5 -7 405.75 57 406 -42 406.25 19 406.5 21 406.75 -7 407 -26 407.25 -13 407.5 -76 407.75 19 408 -8 408.25 39 408.5 11 408.75 -1 409 -21 409.25 -20 409.5 -36 409.75 -13 410 -52 410.25 51 410.5 40 410.75 -1 411 -10 411.25 -11 411.5 32 411.75 19 412 9 412.25 -15 412.5 -37 412.75 -15 413 6 413.25 9 413.5 -17 413.75 18 414 -19 414.25 31 414.5 -58 414.75 17 415 -24 415.25 -13 415.5 52 415.75 22 416 -13 416.25 -23 416.5 -3 416.75 9 417 -14 417.25 13 417.5 3 417.75 -2 418 -12 418.25 21 418.5 24 418.75 7 419 30 419.25 -10 419.5 14 419.75 -9 420 -24 420.25 3 420.5 1 420.75 -3 421 -14 421.25 15 421.5 -21 421.75 -5 422 -41 422.25 1 422.5 2 422.75 -13 423 -1 423.25 -18 423.5 -22 423.75 -5 424 11 424.25 12 424.5 5 424.75 40 425 6 425.25 -21 425.5 -1 425.75 1 426 3 426.25 27 426.5 11 426.75 33 427 -23 427.25 10 427.5 0 427.75 -2 428 7 428.25 15 428.5 -16 428.75 6 429 32 429.25 4 429.5 14 429.75 6 430 15 430.25 -34 430.5 14 430.75 -8 431 -5 431.25 15 431.5 19 431.75 16 432 6 432.25 21 432.5 5 432.75 -10 433 -22 433.25 6 433.5 -8 433.75 -23 434 -22 434.25 28 434.5 34 434.75 42 435 51 435.25 23 435.5 -4 435.75 38 436 -2 436.25 18 436.5 -8 436.75 14 437 20 437.25 8 437.5 35 437.75 -5 438 9 438.25 25 438.5 18 438.75 5 439 -19 439.25 -39 439.5 11 439.75 17 440 9 440.25 -31 440.5 -1 440.75 14 441 -28 441.25 6 441.5 -24 441.75 -22 442 21 442.25 34 442.5 16 442.75 -8 443 -6 443.25 10 443.5 -14 443.75 -11 444 0 444.25 13 444.5 -22 444.75 10 445 39 445.25 24 445.5 15 445.75 1 446 -6 446.25 -16 446.5 -20 446.75 -25 447 1 447.25 6 447.5 -10 447.75 -9 448 -20 448.25 6 448.5 -9 448.75 -34 449 -25 449.25 -1 449.5 -11 449.75 -7 450 -20 450.25 32 450.5 30 450.75 -25 451 -19 451.25 -12 451.5 -6 451.75 -2 452 -8 452.25 29 452.5 -8 452.75 -1 453 0 453.25 -3 453.5 -19 453.75 -16 454 -22 454.25 13 454.5 27 454.75 8 455 3 455.25 4 455.5 9 455.75 0 456 -3 456.25 5 456.5 -4 456.75 22 457 36 457.25 20 457.5 11 457.75 26 458 23 458.25 -18 458.5 27 458.75 -2 459 10 459.25 24 459.5 20 459.75 33 460 -13 460.25 2 460.5 6 460.75 6 461 21 461.25 -27 461.5 9 461.75 1 462 16 462.25 5 462.5 -22 462.75 -6 463 6 463.25 0 463.5 -6 463.75 -20 464 -2 464.25 10 464.5 -1 464.75 10 465 20 465.25 -11 465.5 7 465.75 17 466 10 466.25 12 466.5 -14 466.75 -7 467 -11 467.25 6 467.5 15 467.75 -7 468 -11 468.25 10 468.5 12 468.75 2 469 20 469.25 -10 469.5 -2 469.75 -15 470 14 470.25 23 470.5 -4 470.75 -34 471 11 471.25 2 471.5 -3 471.75 4 472 -10 472.25 -35 472.5 4 472.75 34 473 11 473.25 10 473.5 0 473.75 -10 474 -10 474.25 10 474.5 2 474.75 14 475 -5 475.25 7 475.5 6 475.75 -20 476 -14 476.25 23 476.5 4 476.75 -17 477 13 477.25 13 477.5 19 477.75 44 478 14 478.25 -15 478.5 -5 478.75 0 479 -3 479.25 35 479.5 23 479.75 14 480 -18 480.25 -13 480.5 -25 480.75 -9 481 5 481.25 -7 481.5 19 481.75 28 482 -5 482.25 -35 482.5 3 482.75 -1 483 -40 483.25 -7 483.5 14 483.75 3 484 16 484.25 6 484.5 10 484.75 11 485 8 485.25 22 485.5 12 485.75 0 486 -8 486.25 -13 486.5 12 486.75 -17 487 -10 487.25 8 487.5 0 487.75 22 488 -19 488.25 5 488.5 -2 488.75 -11 489 -29 489.25 -8 489.5 6 489.75 1 490 24 490.25 -40 490.5 22 490.75 32 491 4 491.25 10 491.5 0 491.75 -25 492 -1 492.25 11 492.5 12 492.75 -3 493 1 493.25 -21 493.5 6 493.75 -13 494 -33 494.25 -14 494.5 30 494.75 30 495 -4 495.25 -2 495.5 -12 495.75 -4 496 2 496.25 -5 496.5 -5 496.75 -8 497 -19 497.25 -28 497.5 12 497.75 2 498 19 498.25 -24 498.5 0 498.75 -33 499 -26 499.25 -2 499.5 12 499.75 18 500 -6 500.25 -13 500.5 18 500.75 -18 501 -19 501.25 -5 501.5 -19 501.75 26 502 2 502.25 -9 502.5 21 502.75 -33 503 -1 503.25 -15 503.5 10 503.75 -10 504 14 504.25 -10 504.5 10 504.75 3 505 30 505.25 -26 505.5 -9 505.75 8 506 -21 506.25 -1 506.5 -6 506.75 6 507 -19 507.25 -4 507.5 -24 507.75 3 508 0 508.25 -18 508.5 24 508.75 22 509 14 509.25 -13 509.5 16 509.75 15 510 0 510.25 14 510.5 -15 510.75 -6 511 3 511.25 5 511.5 -14 511.75 0 512 -18 512.25 18 512.5 13 512.75 -7 513 9 513.25 -10 513.5 -2 513.75 1 514 18 514.25 19 514.5 7 514.75 -31 515 -13 515.25 -30 515.5 -40 515.75 -10 516 5 516.25 0 516.5 -7 516.75 6 517 -21 517.25 -1 517.5 -7 517.75 -16 518 11 518.25 -6 518.5 14 518.75 -21 519 -8 519.25 -1 519.5 -5 519.75 -8 520 -34 520.25 2 520.5 -18 520.75 -19 521 -5 521.25 1 521.5 5 521.75 9 522 -20 522.25 0 522.5 7 522.75 6 523 12 523.25 -24 523.5 -27 523.75 -7 524 11 524.25 -6 524.5 -11 524.75 11 525 -35 525.25 -28 525.5 9 525.75 -9 526 -10 526.25 -19 526.5 -10 526.75 9 527 17 527.25 -6 527.5 -26 527.75 -3 528 -7 528.25 -14 528.5 10 528.75 -33 529 1 529.25 -19 529.5 -9 529.75 13 530 -17 530.25 0 530.5 15 530.75 -19 531 -27 531.25 -39 531.5 -25 531.75 31 532 -42 532.25 -16 532.5 -31 532.75 9 533 -37 533.25 -36 533.5 -1 533.75 3 534 -8 534.25 -21 534.5 -24 534.75 -7 535 -23 535.25 1 535.5 -26 535.75 -12 536 -23 536.25 -37 536.5 -20 536.75 -10 537 -27 537.25 -26 537.5 -12 537.75 -2 538 11 538.25 -11 538.5 -28 538.75 0 539 -7 539.25 -20 539.5 -8 539.75 -7 540 15 540.25 -12 540.5 -7 540.75 20 541 -25 541.25 -12 541.5 -28 541.75 -4 542 4 542.25 -1 542.5 10 542.75 -24 543 5 543.25 -17 543.5 -23 543.75 -21 544 -13 544.25 -21 544.5 -26 544.75 -1 545 7 545.25 -32 545.5 -4 545.75 -25 546 -16 546.25 -15 546.5 -2 546.75 -1 547 14 547.25 1 547.5 5 547.75 12 548 -22 548.25 4 548.5 -19 548.75 4 549 -11 549.25 -5 549.5 17 549.75 4 550 -38 550.25 -19 550.5 -17 550.75 -1 551 -25 551.25 -4 551.5 -32 551.75 -26 552 7 552.25 -12 552.5 29 552.75 23 553 -9 553.25 -3 553.5 -6 553.75 -10 554 -6 554.25 15 554.5 -3 554.75 2 555 8 555.25 -12 555.5 -6 555.75 -9 556 -3 556.25 -15 556.5 -4 556.75 -3 557 -2 557.25 -9 557.5 -11 557.75 21 558 5 558.25 11 558.5 1 558.75 1 559 -15 559.25 10 559.5 -23 559.75 19 560 -23 560.25 7 560.5 -35 560.75 -2 561 -4 561.25 -16 561.5 -19 561.75 -4 562 23 562.25 -17 562.5 -13 562.75 -1 563 -5 563.25 -13 563.5 7 563.75 -25 564 19 564.25 -20 564.5 -29 564.75 -7 565 3 565.25 -23 565.5 -27 565.75 -39 566 -30 566.25 -6 566.5 19 566.75 -14 567 16 567.25 -17 567.5 -43 567.75 -27 568 13 568.25 7 568.5 13 568.75 -8 569 0 569.25 -12 569.5 -17 569.75 -21 570 -12 570.25 -5 570.5 7 570.75 -30 571 -39 571.25 -11 571.5 0 571.75 -10 572 10 572.25 -10 572.5 -34 572.75 9 573 4 573.25 -4 573.5 2 573.75 -3 574 -5 574.25 -32 574.5 11 574.75 -26 575 25 575.25 -34 575.5 0 575.75 -16 576 -11 576.25 -18 576.5 -32 576.75 -24 577 -2 577.25 14 577.5 26 577.75 -22 578 13 578.25 -22 578.5 -49 578.75 -17 579 -29 579.25 -24 579.5 18 579.75 -2 580 -28 580.25 2 580.5 -14 580.75 2 581 -8 581.25 -11 581.5 1 581.75 4 582 -2 582.25 0 582.5 -28 582.75 24 583 -27 583.25 -1 583.5 -2 583.75 -14 584 22 584.25 -10 584.5 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