# Optical absorption spectrum of 5,10,15-Triphenylcorrole in dichloromethane # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by M. Taniguchi on 10-01-2004 using a HP 8453. #The absorption values were collected using a spectral bandwidth of 1.0 nm. # # These measurements were scaled to make the molar extinction coefficient match # the value of 110000 cm-1/M at 415.0 nm. These values were # then interpolated to report extinction coefficients at regular 1nm intervals # # The reported molar extinction coefficient is from # Paolesse, R., S. Nardis, F. Sagone and R. G. Khoury (2001) Synthesis and functionalization of meso-aryl-substituted corroles. J. Org. Chem. 66, 550-556. # ##Wavelength (nm) Molar Extinction (cm-1/M) 300 13542 301 13445 302 13321 303 13200 304 13074 305 12934 306 12786 307 12609 308 12427 309 12252 310 12075 311 11899 312 11724 313 11552 314 11373 315 11201 316 11034 317 10887 318 10736 319 10576 320 10420 321 10265 322 10118 323 9965 324 9801 325 9662 326 9525 327 9397 328 9270 329 9176 330 9099 331 9034 332 8991 333 8965 334 8967 335 8987 336 9041 337 9084 338 9165 339 9258 340 9345 341 9446 342 9557 343 9663 344 9778 345 9903 346 10031 347 10168 348 10293 349 10424 350 10547 351 10694 352 10860 353 11014 354 11173 355 11351 356 11525 357 11715 358 11921 359 12072 360 12257 361 12544 362 12819 363 13077 364 13327 365 13498 366 13680 367 14219 368 15081 369 15945 370 16537 371 16901 372 17236 373 17706 374 18306 375 18990 376 19670 377 20442 378 21180 379 22010 380 22835 381 23763 382 24763 383 25814 384 26932 385 28129 386 29350 387 30595 388 31915 389 33192 390 34608 391 36131 392 37654 393 39156 394 40831 395 42809 396 45034 397 47492 398 50417 399 53203 400 56567 401 60350 402 64410 403 68804 404 73663 405 78636 406 83184 407 87610 408 92334 409 96758 410 100207 411 103451 412 106116 413 108200 414 109351 415 109999 416 110265 417 109852 418 109046 419 107699 420 106067 421 103943 422 101524 423 98988 424 96199 425 93431 426 90972 427 88566 428 86330 429 84178 430 82334 431 80717 432 79006 433 76938 434 74795 435 72659 436 69989 437 67149 438 63997 439 60598 440 56965 441 52918 442 49137 443 45212 444 41231 445 37421 446 33632 447 30145 448 26898 449 23783 450 21014 451 18545 452 16250 453 14245 454 12483 455 10854 456 9538 457 8368 458 7349 459 6512 460 5810 461 5149 462 4647 463 4170 464 3700 465 3399 466 3106 467 2973 468 2727 469 2522 470 2382 471 2229 472 2127 473 2049 474 2000 475 1928 476 1911 477 1943 478 1904 479 1906 480 1911 481 1920 482 1950 483 2008 484 1982 485 2032 486 2192 487 2421 488 2433 489 2239 490 2189 491 2198 492 2241 493 2286 494 2381 495 2438 496 2482 497 2564 498 2692 499 2750 500 2832 501 2922 502 3015 503 3147 504 3277 505 3399 506 3501 507 3605 508 3732 509 3834 510 3991 511 4108 512 4205 513 4334 514 4457 515 4551 516 4650 517 4730 518 4841 519 4911 520 5012 521 5046 522 5078 523 5138 524 5211 525 5243 526 5274 527 5307 528 5349 529 5415 530 5507 531 5577 532 5626 533 5750 534 5899 535 6046 536 6206 537 6367 538 6552 539 6744 540 7007 541 7232 542 7479 543 7733 544 8007 545 8315 546 8631 547 8915 548 9206 549 9576 550 9880 551 10189 552 10486 553 10790 554 11077 555 11395 556 11624 557 11896 558 12108 559 12331 560 12516 561 12660 562 12797 563 12922 564 13024 565 13108 566 13183 567 13220 568 13277 569 13356 570 13387 571 13481 572 13502 573 13573 574 13493 575 13538 576 13552 577 13552 578 13353 579 13459 580 13244 581 13157 582 12846 583 12932 584 12630 585 12197 586 12039 587 11780 588 11432 589 11175 590 10834 591 10513 592 10199 593 9864 594 9668 595 9444 596 9159 597 8979 598 8829 599 8665 600 8661 601 8654 602 8677 603 8748 604 8819 605 9024 606 9189 607 9380 608 9584 609 9795 610 9977 611 10199 612 10341 613 10514 614 10604 615 10664 616 10651 617 10623 618 10495 619 10384 620 10208 621 10069 622 9929 623 9711 624 9538 625 9338 626 9089 627 8836 628 8582 629 8422 630 8326 631 8270 632 8228 633 8181 634 8167 635 8175 636 8208 637 8213 638 8252 639 8314 640 8461 641 8612 642 8788 643 8881 644 9008 645 9091 646 9148 647 9141 648 9123 649 9089 650 8975 651 8805 652 8688 653 8458 654 8130 655 8275 656 8062 657 7663 658 7278 659 6661 660 6270 661 5910 662 5542 663 5184 664 4826 665 4481 666 4166 667 3844 668 3557 669 3275 670 3007 671 2755 672 2538 673 2298 674 2106 675 1928 676 1760 677 1602 678 1489 679 1336 680 1238 681 1109 682 994 683 912 684 864 685 800 686 710 687 635 688 583 689 524 690 497 691 448 692 391 693 357 694 321 695 306 696 263 697 260 698 230 699 175 700 156 701 139 702 115 703 107 704 75 705 50 706 24 707 52 708 -8 709 -38 710 -52 711 -67 712 -90 713 -91 714 -95 715 -133 716 -158 717 -182 718 -155 719 -175 720 -186 721 -213 722 -209 723 -221 724 -215 725 -225 726 -219 727 -241 728 -235 729 -215 730 -225 731 -215 732 -248 733 -253 734 -216 735 -244 736 -269 737 -259 738 -300 739 -276 740 -273 741 -334 742 -323 743 -309 744 -357 745 -339 746 -365 747 -368 748 -373 749 -389 750 -347 751 -403 752 -423 753 -422 754 -424 755 -470 756 -432 757 -410 758 -436 759 -533 760 -456 761 -472 762 -595 763 -534 764 -487 765 -476 766 -600 767 -648 768 -547 769 -490 770 -596 771 -564 772 -624 773 -618 774 -608 775 -635 776 -626 777 -632 778 -625 779 -595 780 -641 781 -658 782 -626 783 -698 784 -706 785 -709 786 -699 787 -697 788 -670 789 -713 790 -760 791 -743 792 -739 793 -752 794 -701 795 -698 796 -819 797 -804 798 -739 799 -764 800 -798