# Optical absorption spectrum of 5,10,15-Tris(pentafluorophenyl)corrole in dichloromethane # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by M. Taniguchi on 10-01-2004 using a HP 8453. #The absorption values were collected using a spectral bandwidth of 1.0 nm. # # These measurements were scaled to make the molar extinction coefficient match # the value of 114000 cm-1/M at 408.0 nm. These values were # then interpolated to report extinction coefficients at regular 1nm intervals # # The reported molar extinction coefficient is from # Gross, Z., N. Galili and I. Saltsman (1999) The first direct synthesis of corroles from pyrrole. Angew. Chem. Int. Ed. 38, 1427-1429. # ##Wavelength (nm) Molar Extinction (cm-1/M) 300 11129 301 11128 302 11085 303 11024 304 10964 305 10863 306 10738 307 10595 308 10415 309 10254 310 10091 311 9926 312 9760 313 9594 314 9459 315 9329 316 9195 317 9097 318 9010 319 8934 320 8859 321 8794 322 8733 323 8687 324 8641 325 8625 326 8602 327 8587 328 8570 329 8570 330 8586 331 8575 332 8579 333 8567 334 8544 335 8545 336 8537 337 8513 338 8505 339 8493 340 8468 341 8459 342 8453 343 8439 344 8426 345 8461 346 8487 347 8542 348 8588 349 8638 350 8668 351 8725 352 8814 353 8847 354 8873 355 8922 356 8967 357 9041 358 9111 359 9055 360 9097 361 9249 362 9425 363 9581 364 9791 365 9851 366 9996 367 10630 368 11596 369 12702 370 13530 371 14184 372 14924 373 15839 374 16967 375 18192 376 19482 377 20955 378 22349 379 23821 380 25228 381 26799 382 28352 383 29970 384 31603 385 33302 386 34954 387 36785 388 38744 389 40761 390 43023 391 45621 392 48547 393 51606 394 55089 395 59151 396 63670 397 68667 398 74185 399 79299 400 84752 401 90555 402 96171 403 101311 404 106122 405 109880 406 112309 407 113516 408 114000 409 113564 410 112194 411 110618 412 108649 413 106645 414 104828 415 103330 416 101892 417 100708 418 99854 419 98977 420 97776 421 96077 422 93927 423 91075 424 87259 425 82778 426 77890 427 72128 428 66251 429 59918 430 53710 431 48219 432 42752 433 36779 434 31487 435 27037 436 22735 437 19006 438 15750 439 12885 440 10484 441 8293 442 6625 443 5306 444 4102 445 3162 446 2365 447 1773 448 1281 449 846 450 571 451 332 452 169 453 33 454 -54 455 -170 456 -217 457 -225 458 -262 459 -237 460 -219 461 -247 462 -206 463 -193 464 -252 465 -209 466 -184 467 -34 468 -46 469 -49 470 -16 471 8 472 63 473 131 474 210 475 269 476 348 477 495 478 568 479 660 480 728 481 845 482 932 483 1056 484 1100 485 1203 486 1446 487 1780 488 1831 489 1640 490 1572 491 1607 492 1650 493 1690 494 1805 495 1827 496 1853 497 1926 498 2039 499 2061 500 2124 501 2213 502 2287 503 2445 504 2577 505 2701 506 2843 507 2952 508 3123 509 3265 510 3438 511 3561 512 3676 513 3838 514 3985 515 4095 516 4205 517 4315 518 4453 519 4544 520 4679 521 4786 522 4868 523 4982 524 5121 525 5227 526 5283 527 5360 528 5503 529 5593 530 5694 531 5810 532 5872 533 6034 534 6216 535 6427 536 6627 537 6870 538 7179 539 7543 540 7984 541 8446 542 8984 543 9587 544 10164 545 10806 546 11485 547 12104 548 12697 549 13364 550 13909 551 14385 552 14866 553 15269 554 15654 555 16008 556 16245 557 16555 558 16753 559 17011 560 17084 561 17205 562 17258 563 17246 564 17144 565 16980 566 16706 567 16369 568 15987 569 15549 570 15051 571 14539 572 13925 573 13364 574 12596 575 12005 576 11386 577 10681 578 9910 579 9521 580 8777 581 8208 582 7557 583 7427 584 6847 585 6225 586 6048 587 5769 588 5451 589 5349 590 5147 591 5109 592 5118 593 5185 594 5454 595 5795 596 6045 597 6472 598 6929 599 7308 600 7793 601 8158 602 8439 603 8606 604 8637 605 8669 606 8487 607 8247 608 7907 609 7497 610 6999 611 6543 612 5995 613 5503 614 4987 615 4483 616 4010 617 3551 618 3120 619 2774 620 2432 621 2215 622 2035 623 1855 624 1734 625 1638 626 1482 627 1346 628 1207 629 1143 630 1129 631 1136 632 1100 633 1031 634 966 635 844 636 749 637 576 638 412 639 270 640 201 641 96 642 3 643 -93 644 -152 645 -219 646 -287 647 -415 648 -462 649 -517 650 -574 651 -629 652 -642 653 -702 654 -829 655 -338 656 -296 657 -260 658 -409 659 -815 660 -852 661 -865 662 -874 663 -898 664 -933 665 -947 666 -924 667 -968 668 -956 669 -966 670 -954 671 -949 672 -938 673 -970 674 -965 675 -973 676 -979 677 -984 678 -947 679 -984 680 -968 681 -986 682 -1009 683 -1001 684 -969 685 -959 686 -980 687 -992 688 -984 689 -987 690 -981 691 -973 692 -983 693 -978 694 -975 695 -954 696 -962 697 -924 698 -924 699 -954 700 -948 701 -950 702 -938 703 -940 704 -942 705 -947 706 -948 707 -915 708 -947 709 -969 710 -968 711 -962 712 -979 713 -962 714 -969 715 -974 716 -1001 717 -1005 718 -968 719 -979 720 -999 721 -1016 722 -1005 723 -994 724 -982 725 -982 726 -967 727 -992 728 -963 729 -934 730 -941 731 -919 732 -947 733 -944 734 -891 735 -908 736 -919 737 -901 738 -937 739 -905 740 -888 741 -948 742 -919 743 -896 744 -937 745 -909 746 -917 747 -904 748 -901 749 -911 750 -861 751 -900 752 -919 753 -897 754 -895 755 -935 756 -869 757 -844 758 -853 759 -941 760 -858 761 -853 762 -967 763 -898 764 -840 765 -813 766 -919 767 -964 768 -850 769 -783 770 -875 771 -817 772 -862 773 -866 774 -831 775 -856 776 -845 777 -833 778 -823 779 -775 780 -832 781 -831 782 -784 783 -852 784 -842 785 -856 786 -823 787 -830 788 -795 789 -838 790 -863 791 -855 792 -837 793 -853 794 -790 795 -773 796 -897 797 -884 798 -810 799 -841 800 -856