# Optical absorption spectrum of 5,10-Diaryl chlorin in toluene # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by M. Taniguchi on 10-02-2004 using a HP 8453. #The absorption values were collected using a spectral bandwidth of 1.0 nm. # # These measurements were scaled to make the molar extinction coefficient match # the value of 89100 cm-1/M at 414.0 nm. These values were # then interpolated to report extinction coefficients at regular 1nm intervals # # The reported molar extinction coefficient is from # Strachan, J. -P., D. F. O’Shea, T. Balasubramanian and J. S. Lindsey (2000) Rational synthesis of meso-substituted chlorin building blocks. J. Org. Chem. 65, 3160-3172. # ##Wavelength (nm) Molar Extinction (cm-1/M) 350 14192 351 14627 352 15153 353 15803 354 16506 355 17264 356 18012 357 18709 358 19300 359 19846 360 20273 361 20552 362 20650 363 20544 364 20304 365 19980 366 19598 367 19238 368 18975 369 18802 370 18765 371 18900 372 19201 373 19698 374 20390 375 21262 376 22257 377 23338 378 24491 379 25602 380 26688 381 27777 382 28937 383 30201 384 31568 385 33252 386 35126 387 37487 388 40194 389 43282 390 46815 391 50842 392 55424 393 59979 394 64592 395 68996 396 72959 397 76179 398 78639 399 79891 400 80518 401 80793 402 80669 403 80714 404 80789 405 81144 406 81375 407 81712 408 82221 409 83038 410 84342 411 85788 412 87403 413 88664 414 89100 415 88984 416 88105 417 86426 418 83896 419 79783 420 73814 421 66179 422 57647 423 49051 424 40526 425 32761 426 26075 427 20236 428 15804 429 12240 430 9424 431 7464 432 5928 433 4689 434 3807 435 3185 436 2703 437 2357 438 2075 439 1881 440 1747 441 1632 442 1556 443 1502 444 1458 445 1442 446 1431 447 1437 448 1446 449 1469 450 1497 451 1537 452 1572 453 1609 454 1640 455 1674 456 1722 457 1776 458 1827 459 1869 460 1906 461 1940 462 1970 463 1989 464 2016 465 2008 466 2007 467 1993 468 2010 469 2018 470 2011 471 2020 472 2054 473 2081 474 2101 475 2121 476 2142 477 2167 478 2207 479 2233 480 2273 481 2312 482 2370 483 2450 484 2553 485 2733 486 2954 487 3086 488 3318 489 3729 490 4198 491 4707 492 5236 493 5713 494 6093 495 6394 496 6606 497 6760 498 6879 499 7021 500 7154 501 7327 502 7562 503 7817 504 8077 505 8310 506 8491 507 8611 508 8671 509 8680 510 8617 511 8448 512 8145 513 7709 514 7170 515 6573 516 5930 517 5311 518 4713 519 4183 520 3727 521 3327 522 2989 523 2712 524 2508 525 2379 526 2296 527 2279 528 2304 529 2372 530 2465 531 2560 532 2626 533 2648 534 2589 535 2493 536 2393 537 2308 538 2235 539 2159 540 2068 541 1952 542 1830 543 1691 544 1550 545 1434 546 1321 547 1227 548 1123 549 1015 550 913 551 832 552 764 553 700 554 650 555 608 556 580 557 559 558 545 559 516 560 501 561 484 562 465 563 451 564 435 565 421 566 409 567 416 568 433 569 448 570 485 571 521 572 569 573 614 574 683 575 739 576 802 577 920 578 1045 579 1202 580 1423 581 1696 582 1966 583 2185 584 2432 585 2665 586 2802 587 2940 588 3059 589 3097 590 3081 591 2981 592 2825 593 2642 594 2428 595 2195 596 1970 597 1740 598 1562 599 1415 600 1310 601 1230 602 1167 603 1113 604 1060 605 998 606 951 607 908 608 881 609 874 610 875 611 863 612 853 613 853 614 852 615 855 616 858 617 857 618 877 619 907 620 980 621 1081 622 1274 623 1571 624 1967 625 2468 626 2994 627 3496 628 3908 629 4189 630 4381 631 4566 632 4875 633 5507 634 6765 635 8911 636 12056 637 16070 638 20389 639 24122 640 26475 641 26967 642 25504 643 22653 644 18955 645 15093 646 11573 647 8646 648 6392 649 4711 650 3538 651 2726 652 2167 653 1762 654 1459 655 1175 656 1066 657 793 658 580 659 487 660 371 661 285 662 210 663 160 664 117 665 90 666 72 667 50 668 43 669 31 670 20 671 19 672 12 673 6 674 0 675 -4 676 -5 677 -6 678 -7 679 -18 680 -18 681 -16 682 -14 683 -20 684 -25 685 -20 686 -26 687 -23 688 -28 689 -31 690 -29 691 -31 692 -32 693 -33 694 -35 695 -40 696 -38 697 -32 698 -32 699 -38 700 -38 701 -36 702 -31 703 -36 704 -35 705 -39 706 -35 707 -29 708 -36 709 -35 710 -36 711 -34 712 -32 713 -32 714 -34 715 -36 716 -38 717 -34 718 -32 719 -34 720 -35 721 -32 722 -30 723 -34 724 -33 725 -33 726 -35 727 -31 728 -32 729 -32 730 -32 731 -34 732 -33 733 -34 734 -31 735 -35 736 -32 737 -32 738 -36 739 -32 740 -38 741 -35 742 -38 743 -32 744 -41 745 -34 746 -37 747 -31 748 -31 749 -36 750 -34 751 -31 752 -31 753 -32 754 -31 755 -32 756 -32 757 -27 758 -26 759 -25 760 -29 761 -29 762 -30 763 -27 764 -27 765 -28 766 -37 767 -36 768 -27 769 -25 770 -30 771 -32 772 -32 773 -33 774 -32 775 -31 776 -35 777 -28 778 -30 779 -31 780 -32 781 -36 782 -32 783 -28 784 -27 785 -32 786 -36 787 -26 788 -28 789 -32 790 -31 791 -31 792 -33 793 -29 794 -24 795 -34 796 -32 797 -31 798 -30 799 -27 800 -31