# Optical absorption spectrum of 5,10-Diaryl Cu-oxochlorin in toluene # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by M. Taniguchi on 10-02-2004 using a HP 8453. #The absorption values were collected using a spectral bandwidth of 1.0 nm. # # These measurements were scaled to make the molar extinction coefficient match # the value of 174000 cm-1/M at 419.0 nm. These values were # then interpolated to report extinction coefficients at regular 1nm intervals # # The reported molar extinction coefficient is from # Taniguchi, M., H.-J. Kim, D. Ra, J. K. Schwartz, C. Kirmaier, E. Hindin, J. R. Diers, S. Prathapan, D. F. Bocian, D. Holten and J. S. Lindsey (2002) Synthesis and electronic properties of regioisomerically pure oxochlorins. J. Org. Chem. 67, 7329-7342. # ##Wavelength (nm) Molar Extinction (cm-1/M) 351 7835 352 7788 353 7784 354 7791 355 7806 356 7850 357 7927 358 7992 359 8100 360 8218 361 8370 362 8524 363 8694 364 8813 365 9004 366 9142 367 9337 368 9592 369 9809 370 10022 371 10186 372 10330 373 10493 374 10649 375 10796 376 10984 377 11161 378 11378 379 11613 380 11906 381 12255 382 12656 383 13200 384 13857 385 14673 386 15619 387 16767 388 18064 389 19473 390 21000 391 22641 392 24347 393 25914 394 27389 395 28698 396 29867 397 30825 398 31518 399 31986 400 32286 401 32585 402 33012 403 33745 404 35011 405 36952 406 39696 407 43610 408 49057 409 56105 410 64249 411 74175 412 85963 413 98803 414 112490 415 127353 416 142489 417 156487 418 167132 419 173999 420 177139 421 173987 422 165431 423 152371 424 135735 425 117260 426 99101 427 81327 428 66475 429 53419 430 42529 431 34383 432 27697 433 21985 434 17665 435 14484 436 11879 437 9842 438 8226 439 6977 440 5984 441 5137 442 4496 443 3973 444 3546 445 3191 446 2887 447 2637 448 2417 449 2251 450 2108 451 1970 452 1856 453 1779 454 1682 455 1609 456 1549 457 1493 458 1431 459 1388 460 1365 461 1334 462 1334 463 1309 464 1288 465 1288 466 1295 467 1292 468 1279 469 1298 470 1287 471 1308 472 1323 473 1341 474 1348 475 1351 476 1379 477 1395 478 1413 479 1425 480 1435 481 1451 482 1467 483 1468 484 1483 485 1495 486 1519 487 1535 488 1538 489 1557 490 1573 491 1599 492 1652 493 1674 494 1691 495 1745 496 1794 497 1852 498 1901 499 1954 500 2026 501 2092 502 2156 503 2225 504 2307 505 2357 506 2439 507 2488 508 2540 509 2601 510 2652 511 2717 512 2756 513 2787 514 2816 515 2854 516 2859 517 2858 518 2837 519 2838 520 2817 521 2769 522 2739 523 2730 524 2730 525 2734 526 2741 527 2763 528 2796 529 2815 530 2846 531 2870 532 2889 533 2919 534 2926 535 2916 536 2915 537 2916 538 2905 539 2879 540 2888 541 2903 542 2908 543 2933 544 2973 545 3034 546 3102 547 3205 548 3362 549 3529 550 3719 551 3950 552 4168 553 4391 554 4597 555 4792 556 4958 557 5085 558 5192 559 5284 560 5316 561 5306 562 5254 563 5183 564 5099 565 5003 566 4889 567 4789 568 4686 569 4588 570 4508 571 4445 572 4369 573 4319 574 4294 575 4272 576 4264 577 4276 578 4269 579 4291 580 4296 581 4310 582 4320 583 4349 584 4409 585 4500 586 4616 587 4773 588 4975 589 5195 590 5523 591 5899 592 6386 593 7003 594 7724 595 8691 596 9874 597 11370 598 13173 599 15193 600 17356 601 19507 602 21517 603 23182 604 24268 605 24775 606 24657 607 23940 608 22733 609 21182 610 19420 611 17550 612 15727 613 13946 614 12283 615 10785 616 9449 617 8262 618 7246 619 6382 620 5622 621 4982 622 4423 623 3928 624 3500 625 3117 626 2805 627 2523 628 2270 629 2051 630 1871 631 1695 632 1539 633 1416 634 1288 635 1167 636 1067 637 969 638 868 639 784 640 720 641 646 642 596 643 550 644 489 645 447 646 411 647 376 648 332 649 301 650 282 651 235 652 210 653 201 654 150 655 155 656 171 657 25 658 54 659 63 660 53 661 32 662 20 663 17 664 8 665 -8 666 -19 667 -33 668 -33 669 -41 670 -58 671 -57 672 -62 673 -65 674 -70 675 -71 676 -86 677 -83 678 -87 679 -91 680 -96 681 -102 682 -111 683 -107 684 -105 685 -113 686 -116 687 -126 688 -117 689 -118 690 -119 691 -124 692 -132 693 -129 694 -129 695 -122 696 -127 697 -136 698 -132 699 -138 700 -131 701 -136 702 -130 703 -134 704 -142 705 -144 706 -146 707 -135 708 -140 709 -141 710 -148 711 -136 712 -155 713 -149 714 -151 715 -148 716 -150 717 -150 718 -150 719 -157 720 -150 721 -151 722 -153 723 -150 724 -151 725 -157 726 -149 727 -155 728 -156 729 -153 730 -151 731 -148 732 -151 733 -155 734 -145 735 -157 736 -159 737 -154 738 -157 739 -152 740 -157 741 -160 742 -164 743 -154 744 -157 745 -160 746 -159 747 -152 748 -151 749 -152 750 -157 751 -159 752 -161 753 -153 754 -157 755 -155 756 -152 757 -163 758 -151 759 -154 760 -153 761 -157 762 -158 763 -147 764 -150 765 -148 766 -147 767 -153 768 -149 769 -147 770 -146 771 -141 772 -151 773 -144 774 -147 775 -146 776 -140 777 -148 778 -141 779 -134 780 -135 781 -131 782 -131 783 -128 784 -137 785 -141 786 -127 787 -130 788 -123 789 -127 790 -129 791 -137 792 -135 793 -144 794 -138 795 -149 796 -149 797 -149 798 -154 799 -145 800 -154