# Optical absorption spectrum of 5,10-Diaryl Zn-chlorin in toluene # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by M. Taniguchi on 10-02-2004 using a HP 8453. #The absorption values were collected using a spectral bandwidth of 1.0 nm. # # These measurements were scaled to make the molar extinction coefficient match # the value of 186000 cm-1/M at 412.0 nm. These values were # then interpolated to report extinction coefficients at regular 1nm intervals # # The reported molar extinction coefficient is from # Strachan, J. -P., D. F. O’Shea, T. Balasubramanian and J. S. Lindsey (2000) Rational synthesis of meso-substituted chlorin building blocks. J. Org. Chem. 65, 3160-3172. # ##Wavelength (nm) Molar Extinction (cm-1/M) 350 9514 351 9570 352 9613 353 9665 354 9684 355 9691 356 9630 357 9636 358 9641 359 9617 360 9538 361 9476 362 9466 363 9488 364 9639 365 9934 366 10059 367 10092 368 10167 369 10289 370 10402 371 10517 372 10694 373 10870 374 11115 375 11460 376 11903 377 12564 378 13453 379 14507 380 15837 381 17528 382 19593 383 21889 384 24402 385 27099 386 29765 387 32524 388 34893 389 36860 390 38290 391 39172 392 39576 393 39467 394 39219 395 38881 396 38878 397 39548 398 41256 399 44088 400 48359 401 54490 402 62475 403 72746 404 85673 405 100676 406 117139 407 134303 408 152427 409 169065 410 180663 411 186745 412 186000 413 178237 414 164504 415 146179 416 125720 417 104950 418 85575 419 68471 420 53719 421 41448 422 31993 423 25011 424 19369 425 15074 426 11857 427 9351 428 7643 429 6397 430 5392 431 4746 432 4292 433 3859 434 3481 435 3293 436 3082 437 2934 438 2814 439 2717 440 2645 441 2554 442 2494 443 2467 444 2420 445 2411 446 2385 447 2380 448 2373 449 2304 450 2300 451 2322 452 2294 453 2273 454 2253 455 2236 456 2230 457 2235 458 2229 459 2207 460 2194 461 2203 462 2247 463 2220 464 2238 465 2235 466 2269 467 2300 468 2348 469 2387 470 2403 471 2366 472 2409 473 2411 474 2433 475 2425 476 2390 477 2406 478 2403 479 2366 480 2326 481 2286 482 2271 483 2272 484 2253 485 2232 486 2172 487 2302 488 2405 489 2361 490 2378 491 2456 492 2548 493 2621 494 2720 495 2864 496 2979 497 3103 498 3322 499 3532 500 3759 501 4029 502 4280 503 4489 504 4691 505 4845 506 4909 507 4919 508 4840 509 4780 510 4691 511 4629 512 4550 513 4461 514 4376 515 4320 516 4226 517 4132 518 4006 519 3907 520 3841 521 3765 522 3694 523 3619 524 3562 525 3519 526 3488 527 3424 528 3365 529 3284 530 3256 531 3230 532 3185 533 3170 534 3113 535 3070 536 3036 537 2988 538 2923 539 2853 540 2806 541 2735 542 2685 543 2629 544 2573 545 2529 546 2535 547 2586 548 2591 549 2625 550 2680 551 2804 552 2936 553 3091 554 3338 555 3614 556 3940 557 4301 558 4675 559 5076 560 5393 561 5668 562 5854 563 5901 564 5827 565 5688 566 5518 567 5371 568 5333 569 5312 570 5360 571 5428 572 5473 573 5474 574 5378 575 5255 576 5064 577 4877 578 4692 579 4568 580 4369 581 4212 582 4033 583 3993 584 3846 585 3730 586 3715 587 3743 588 3849 589 4074 590 4364 591 4726 592 5148 593 5537 594 5961 595 6359 596 6783 597 7328 598 8147 599 9318 600 11061 601 13463 602 16647 603 20661 604 25059 605 29757 606 34102 607 37252 608 38890 609 38723 610 36825 611 33483 612 29364 613 24873 614 20483 615 16560 616 13193 617 10404 618 8261 619 6647 620 5397 621 4515 622 3784 623 3251 624 2813 625 2494 626 2238 627 2007 628 1837 629 1675 630 1558 631 1458 632 1364 633 1254 634 1150 635 1079 636 1028 637 962 638 929 639 909 640 890 641 870 642 844 643 838 644 808 645 801 646 790 647 791 648 779 649 754 650 740 651 757 652 763 653 743 654 732 655 730 656 621 657 829 658 804 659 719 660 721 661 723 662 708 663 722 664 703 665 715 666 733 667 715 668 722 669 716 670 717 671 722 672 724 673 729 674 724 675 721 676 715 677 732 678 720 679 718 680 704 681 730 682 730 683 727 684 709 685 724 686 727 687 734 688 733 689 738 690 734 691 730 692 744 693 757 694 751 695 746 696 747 697 763 698 761 699 769 700 770 701 781 702 786 703 771 704 791 705 786 706 786 707 789 708 785 709 789 710 783 711 789 712 796 713 793 714 787 715 781 716 781 717 783 718 777 719 788 720 785 721 782 722 784 723 788 724 792 725 780 726 777 727 795 728 805 729 801 730 793 731 796 732 814 733 809 734 813 735 816 736 814 737 820 738 821 739 821 740 820 741 819 742 827 743 839 744 814 745 825 746 825 747 833 748 824 749 818 750 828 751 826 752 828 753 826 754 827 755 827 756 819 757 846 758 841 759 847 760 846 761 848 762 852 763 856 764 856 765 861 766 856 767 861 768 874 769 874 770 887 771 878 772 896 773 913 774 902 775 901 776 898 777 921 778 915 779 923 780 915 781 918 782 910 783 922 784 922 785 916 786 905 787 921 788 928 789 904 790 900 791 911 792 893 793 907 794 898 795 886 796 879 797 881 798 890 799 877 800 870