# Optical absorption spectrum of Bis(5-phenyldipyrrinato)zinc in toluene # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by D. Holten on 09-15-2004 using a . # # # These measurements were scaled to make the molar extinction coefficient match # the value of 115000 cm-1/M at 485.0 nm. These values were # then interpolated to report extinction coefficients at regular 1nm intervals # # The reported molar extinction coefficient is from # Sazanovich, I. V., C. Kirmaier, E. Hindin, L. Yu, D. Bocian, J. S. Lindsey and D. Holten (2004) Structural control of the excited-state dynamics of bis(dipyrrinato)zinc complexes: self-assembling chromophores for light-harvesting architecture. J. Am. Chem. Soc. 126, 2664-2665. # ##Wavelength (nm) Molar Extinction (cm-1/M) 290 10232 290.5 10348 291 10227 291.5 10176 292 10116 292.5 10134 293 10120 293.5 10059 294 10094 294.5 10055 295 10093 295.5 10073 296 10059 296.5 10074 297 10109 297.5 10192 298 10233 298.5 10265 299 10334 299.5 10347 300 10384 300.5 10475 301 10509 301.5 10616 302 10732 302.5 10818 303 10910 303.5 11087 304 11137 304.5 11199 305 11330 305.5 11383 306 11537 306.5 11687 307 11818 307.5 11896 308 11984 308.5 12166 309 12322 309.5 12465 310 12575 310.5 12630 311 12805 311.5 12935 312 12977 312.5 13132 313 13214 313.5 13324 314 13408 314.5 13559 315 13633 315.5 13612 316 13791 316.5 13835 317 13887 317.5 13953 318 14013 318.5 14015 319 14051 319.5 14106 320 14105 320.5 14215 321 14097 321.5 14138 322 14075 322.5 14070 323 14025 323.5 13937 324 13942 324.5 13814 325 13730 325.5 13632 326 13498 326.5 13394 327 13288 327.5 13144 328 13028 328.5 12866 329 12703 329.5 12564 330 12423 330.5 12311 331 12069 331.5 11947 332 11809 332.5 11623 333 11518 333.5 11345 334 11199 334.5 11025 335 10913 335.5 10753 336 10662 336.5 10455 337 10398 337.5 10308 338 10156 338.5 10028 339 9939 339.5 9823 340 9772 340.5 9650 341 9524 341.5 9485 342 9382 342.5 9314 343 9272 343.5 9169 344 9141 344.5 9089 345 8981 345.5 8979 346 8903 346.5 8875 347 8810 347.5 8834 348 8804 348.5 8701 349 8722 349.5 8602 350 8636 350.5 8654 351 8647 351.5 8590 352 8516 352.5 8566 353 8574 353.5 8479 354 8401 354.5 8521 355 8492 355.5 8416 356 8350 356.5 8377 357 8311 357.5 8258 358 8200 358.5 8113 359 8023 359.5 8034 360 7957 360.5 7903 361 7839 361.5 7784 362 7634 362.5 7611 363 7576 363.5 7463 364 7363 364.5 7305 365 7229 365.5 7136 366 7091 366.5 7000 367 6913 367.5 6856 368 6798 368.5 6699 369 6647 369.5 6546 370 6523 370.5 6474 371 6347 371.5 6339 372 6275 372.5 6200 373 6159 373.5 6049 374 6051 374.5 5931 375 5899 375.5 5877 376 5739 376.5 5700 377 5648 377.5 5567 378 5515 378.5 5474 379 5378 379.5 5274 380 5251 380.5 5174 381 5086 381.5 4997 382 4923 382.5 4811 383 4701 383.5 4672 384 4542 384.5 4413 385 4368 385.5 4251 386 4146 386.5 4038 387 3945 387.5 3850 388 3765 388.5 3686 389 3581 389.5 3445 390 3373 390.5 3273 391 3179 391.5 3071 392 3006 392.5 2903 393 2807 393.5 2764 394 2674 394.5 2587 395 2584 395.5 2505 396 2427 396.5 2429 397 2397 397.5 2302 398 2246 398.5 2240 399 2228 399.5 2192 400 2174 400.5 2152 401 2079 401.5 2125 402 2125 402.5 2095 403 2081 403.5 2136 404 2138 404.5 2091 405 2132 405.5 2164 406 2137 406.5 2208 407 2245 407.5 2228 408 2274 408.5 2347 409 2370 409.5 2369 410 2424 410.5 2473 411 2520 411.5 2537 412 2629 412.5 2659 413 2719 413.5 2770 414 2833 414.5 2866 415 2945 415.5 3042 416 3100 416.5 3172 417 3268 417.5 3324 418 3387 418.5 3522 419 3610 419.5 3683 420 3848 420.5 3937 421 4035 421.5 4166 422 4311 422.5 4422 423 4555 423.5 4761 424 4870 424.5 5031 425 5263 425.5 5401 426 5574 426.5 5792 427 6039 427.5 6199 428 6434 428.5 6675 429 6905 429.5 7167 430 7415 430.5 7687 431 7954 431.5 8267 432 8564 432.5 8834 433 9162 433.5 9501 434 9812 434.5 10107 435 10456 435.5 10826 436 11126 436.5 11488 437 11874 437.5 12160 438 12506 438.5 12939 439 13283 439.5 13597 440 14031 440.5 14403 441 14732 441.5 15156 442 15584 442.5 15938 443 16387 443.5 16830 444 17277 444.5 17790 445 18320 445.5 18852 446 19428 446.5 20092 447 20724 447.5 21399 448 22149 448.5 23010 449 23769 449.5 24733 450 25705 450.5 26741 451 27789 451.5 29006 452 30207 452.5 31503 453 32855 453.5 34351 454 35823 454.5 37421 455 39025 455.5 40767 456 42456 456.5 44268 457 46031 457.5 47827 458 49589 458.5 51346 459 53015 459.5 54638 460 56171 460.5 57637 461 58863 461.5 60108 462 61099 462.5 61976 463 62718 463.5 63367 464 63791 464.5 64220 465 64507 465.5 64732 466 64857 466.5 65025 467 65075 467.5 65126 468 65254 468.5 65410 469 65521 469.5 65725 470 66094 470.5 66486 471 66956 471.5 67672 472 68503 472.5 69492 473 70645 473.5 72035 474 73542 474.5 75348 475 77291 475.5 79490 476 81786 476.5 84353 477 86904 477.5 89639 478 92391 478.5 95209 479 97874 479.5 100618 480 103135 480.5 105553 481 107596 481.5 109601 482 111251 482.5 112526 483 113613 483.5 114425 484 114864 484.5 115090 485 115000 485.5 114583 486 114011 486.5 113189 487 112110 487.5 110699 488 109227 488.5 107409 489 105464 489.5 103231 490 100939 490.5 98342 491 95655 491.5 92725 492 89734 492.5 86422 493 83201 493.5 79716 494 76212 494.5 72593 495 69052 495.5 65377 496 61803 496.5 58174 497 54721 497.5 51243 498 47915 498.5 44658 499 41587 499.5 38583 500 35808 500.5 33092 501 30603 501.5 28152 502 25931 502.5 23769 503 21820 503.5 19967 504 18276 504.5 16668 505 15289 505.5 13893 506 12655 506.5 11536 507 10505 507.5 9498 508 8682 508.5 7875 509 7110 509.5 6473 510 5877 510.5 5310 511 4788 511.5 4409 512 3967 512.5 3576 513 3284 513.5 2964 514 2676 514.5 2452 515 2237 515.5 2002 516 1840 516.5 1694 517 1530 517.5 1354 518 1246 518.5 1177 519 1051 519.5 963 520 909 520.5 807 521 741 521.5 687 522 652 522.5 588 523 547 523.5 542 524 447 524.5 422 525 415 525.5 367 526 352 526.5 367 527 311 527.5 277 528 291 528.5 293 529 241 529.5 239 530 234 530.5 208 531 194 531.5 210 532 210 532.5 173 533 192 533.5 184 534 163 534.5 147 535 169 535.5 139 536 148 536.5 169 537 136 537.5 153 538 162 538.5 166 539 116 539.5 145 540 154 540.5 141 541 134 541.5 145 542 140 542.5 131 543 149 543.5 143 544 130 544.5 146 545 143 545.5 119 546 113 546.5 155 547 119 547.5 104 548 121 548.5 134 549 104 549.5 107 550 145