# Emission spectrum of in toluene # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by on on 10-01-2004 # using a PTI QM-4/2003 SE. The excitation and emission monochromators were set at 0.25 mm, giving a spectral bandwidth of 1 nm. The data interval was 1 nm and the integration time was 1 sec. Samples were prepared in 1cm pathlength quartz cells with absorbance less than 0.1 at the excitation and all emission wavelengths to uniformly illuminate across the sample, and to avoid the inner-filter effect. The dark counts were subtracted and the spectra were corrected for wavelength-dependent instrument sensitivity. # ##Wavelength (nm) Emission (AU) 500 14500 501 15700 502 17200 503 18700 504 20600 505 23000 506 26400 507 29200 508 33400 509 37300 510 43600 511 49100 512 56300 513 64400 514 75100 515 85900 516 100000 517 115000 518 136000 519 155000 520 182000 521 210000 522 248000 523 287000 524 338000 525 394000 526 464000 527 540000 528 638000 529 749000 530 892000 531 1030000 532 1210000 533 1400000 534 1630000 535 1860000 536 2140000 537 2440000 538 2800000 539 3170000 540 3610000 541 4080000 542 4600000 543 5100000 544 5710000 545 6300000 546 6990000 547 7680000 548 8430000 549 9160000 550 9970000 551 10700000 552 11600000 553 12400000 554 13300000 555 14100000 556 14900000 557 15600000 558 16300000 559 17000000 560 17600000 561 18300000 562 18800000 563 19400000 564 19900000 565 20300000 566 20800000 567 21200000 568 21500000 569 21900000 570 22100000 571 22400000 572 22600000 573 22800000 574 22900000 575 23000000 576 23100000 577 23100000 578 23100000 579 23100000 580 23000000 581 23000000 582 22900000 583 22800000 584 22700000 585 22500000 586 22400000 587 22200000 588 22100000 589 21900000 590 21700000 591 21600000 592 21400000 593 21200000 594 21100000 595 21000000 596 20800000 597 20700000 598 20600000 599 20500000 600 20400000 601 20300000 602 20200000 603 20200000 604 20200000 605 20100000 606 20100000 607 20100000 608 20100000 609 20100000 610 20100000 611 20100000 612 20100000 613 20000000 614 20000000 615 20000000 616 19900000 617 19900000 618 19800000 619 19800000 620 19700000 621 19700000 622 19600000 623 19500000 624 19400000 625 19200000 626 18900000 627 18800000 628 18500000 629 18300000 630 18100000 631 17800000 632 17600000 633 17400000 634 17100000 635 16800000 636 16500000 637 16200000 638 15900000 639 15600000 640 15300000 641 15000000 642 14600000 643 14400000 644 14000000 645 13800000 646 13500000 647 13200000 648 12900000 649 12600000 650 12300000 651 12100000 652 11800000 653 11600000 654 11400000 655 11100000 656 10900000 657 10700000 658 10500000 659 10300000 660 10100000 661 9910000 662 9710000 663 9560000 664 9370000 665 9220000 666 9060000 667 8950000 668 8800000 669 8670000 670 8510000 671 8430000 672 8270000 673 8130000 674 8000000 675 7880000 676 7730000 677 7620000 678 7480000 679 7370000 680 7250000 681 7120000 682 7000000 683 6880000 684 6730000 685 6620000 686 6500000 687 6390000 688 6250000 689 6160000 690 6020000 691 5910000 692 5800000 693 5670000 694 5570000 695 5460000 696 5320000 697 5220000 698 5090000 699 4970000 700 4850000 701 4730000 702 4620000 703 4520000 704 4420000 705 4310000 706 4200000 707 4100000 708 3990000 709 3900000 710 3800000 711 3700000 712 3600000 713 3510000 714 3430000 715 3350000 716 3270000 717 3190000 718 3120000 719 3040000 720 2960000 721 2890000 722 2810000 723 2750000 724 2680000 725 2620000 726 2550000 727 2510000 728 2450000 729 2390000 730 2330000 731 2290000 732 2220000 733 2180000 734 2130000 735 2080000 736 2030000 737 2010000 738 1940000 739 1920000 740 1870000 741 1840000 742 1800000 743 1770000 744 1730000 745 1690000 746 1650000 747 1620000 748 1570000 749 1540000 750 1500000 751 1480000 752 1440000 753 1410000 754 1390000 755 1360000 756 1320000 757 1300000 758 1260000 759 1240000 760 1210000 761 1190000 762 1160000 763 1140000 764 1110000 765 1090000 766 1070000 767 1050000 768 1020000 769 1000000 770 983000 771 969000 772 944000 773 920000 774 909000 775 885000 776 864000 777 846000 778 832000 779 804000 780 793000 781 775000 782 756000 783 735000 784 724000 785 709000 786 697000 787 678000 788 661000 789 646000 790 629000 791 615000 792 608000 793 596000 794 571000 795 570000 796 563000 797 547000 798 537000 799 527000 800 509000