# Optical absorption spectrum of Perylene-monoimide, [PMI-2] in toluene # # Data from PhotochemCAD 2.1a has been munged on 2 June 2017 by Scott Prahl to make # the information available to non-Windows users. Although I have tried to be as careful # as possible, I may have introduced some error; the cautious user is advised to compare # these results with the original sources at www.photochemcad.com: # # H. Du, R. A. Fuh, J. Li, A. Corkan, J. S. Lindsey, "PhotochemCAD: A computer-aided design # and research tool in photochemistry," Photochem. Photobiol., 68, 141-142, 1998. # J. M. Dixon, M. Taniguchi and J. S. Lindsey "PhotochemCAD 2. A refined program with accompanying # spectral databases for photochemical calculations", Photochem. Photobiol., 81, 212-213, 2005. # # The spectral absorption measurements were made by M. Taniguchi on 10-01-2004 using a HP 8453. #The absorption values were collected using a spectral bandwidth of 1.0 nm. # # These measurements were scaled to make the molar extinction coefficient match # the value of 32000 cm-1/M at 511.0 nm. These values were # then interpolated to report extinction coefficients at regular 1nm intervals # # The reported molar extinction coefficient is from # Tomizaki, K., R. S. Loewe, C. Kirmaier, J. K. Schwartz, J. L. Retsek, D. F. Bocian, D. Holten and J. S. Lindsey (2002) Synthesis and photophysical properties of light-harvesting arrays comprised of a porphyrin bearing multiple perylene-monoimide accessory pigments. J. Org. Chem. 67, 6519-6534. # ##Wavelength (nm) Molar Extinction (cm-1/M) 300 4219 301 4125 302 4038 303 3959 304 3872 305 3782 306 3691 307 3609 308 3528 309 3453 310 3386 311 3334 312 3294 313 3259 314 3230 315 3204 316 3184 317 3166 318 3143 319 3116 320 3087 321 3051 322 3019 323 2988 324 2959 325 2931 326 2908 327 2891 328 2886 329 2891 330 2910 331 2934 332 2959 333 2986 334 3024 335 3056 336 3103 337 3143 338 3178 339 3201 340 3192 341 3159 342 3103 343 3041 344 2983 345 2950 346 2942 347 2950 348 2986 349 3051 350 3139 351 3259 352 3388 353 3526 354 3669 355 3776 356 3801 357 3724 358 3563 359 3340 360 3112 361 2895 362 2716 363 2563 364 2440 365 2348 366 2272 367 2208 368 2157 369 2133 370 2116 371 2094 372 2072 373 2039 374 2006 375 1979 376 1958 377 1946 378 1933 379 1921 380 1933 381 1939 382 1954 383 1969 384 1981 385 1991 386 2001 387 2012 388 2028 389 2047 390 2059 391 2074 392 2087 393 2101 394 2124 395 2161 396 2213 397 2278 398 2355 399 2435 400 2529 401 2633 402 2744 403 2872 404 3005 405 3158 406 3318 407 3473 408 3626 409 3759 410 3895 411 4018 412 4145 413 4300 414 4470 415 4659 416 4868 417 5105 418 5351 419 5607 420 5870 421 6142 422 6425 423 6708 424 6974 425 7263 426 7531 427 7778 428 8065 429 8327 430 8586 431 8924 432 9249 433 9544 434 9882 435 10304 436 10718 437 11191 438 11716 439 12261 440 12855 441 13411 442 14047 443 14678 444 15311 445 15959 446 16533 447 17141 448 17671 449 18167 450 18640 451 19074 452 19437 453 19774 454 20054 455 20284 456 20558 457 20769 458 21055 459 21388 460 21789 461 22179 462 22719 463 23201 464 23838 465 24559 466 25410 467 26336 468 27152 469 28176 470 29110 471 30000 472 30833 473 31636 474 32434 475 33026 476 33586 477 34083 478 34226 479 34411 480 34220 481 34217 482 33791 483 33406 484 32871 485 31827 486 31366 487 32221 488 30981 489 30306 490 29918 491 29648 492 29509 493 29405 494 29558 495 29801 496 29940 497 30530 498 30899 499 31429 500 32049 501 32625 502 33029 503 33504 504 33931 505 34157 506 34269 507 34362 508 33917 509 33584 510 32854 511 31999 512 31024 513 29760 514 28476 515 26944 516 25232 517 23622 518 21918 519 20114 520 18521 521 16802 522 15268 523 13764 524 12368 525 11122 526 9920 527 8865 528 7874 529 6965 530 6176 531 5443 532 4775 533 4168 534 3659 535 3190 536 2793 537 2426 538 2105 539 1840 540 1623 541 1435 542 1269 543 1146 544 1040 545 946 546 883 547 823 548 775 549 736 550 708 551 686 552 661 553 640 554 628 555 614 556 600 557 590 558 589 559 582 560 571 561 559 562 553 563 555 564 553 565 543 566 548 567 540 568 534 569 525 570 521 571 516 572 515 573 509 574 507 575 503 576 508 577 505 578 497 579 500 580 501 581 493 582 490 583 493 584 497 585 495 586 490 587 495 588 495 589 492 590 496 591 496 592 496 593 493 594 491 595 494 596 492 597 493 598 494 599 491 600 493 601 487 602 489 603 491 604 491 605 491 606 491 607 489 608 484 609 491 610 490 611 487 612 488 613 494 614 487 615 490 616 490 617 492 618 491 619 491 620 489 621 492 622 492 623 493 624 490 625 495 626 494 627 493 628 490 629 493 630 493 631 497 632 497 633 497 634 498 635 499 636 496 637 490 638 487 639 488 640 492 641 495 642 491 643 492 644 490 645 498 646 495 647 492 648 491 649 490 650 492 651 492 652 489 653 490 654 494 655 464 656 456 657 452 658 472 659 491 660 496 661 488 662 487 663 487 664 494 665 490 666 489 667 489 668 489 669 489 670 488 671 489 672 482 673 482 674 486 675 486 676 483 677 483 678 486 679 481 680 482 681 481 682 480 683 480 684 480 685 480 686 481 687 476 688 480 689 478 690 480 691 477 692 480 693 480 694 479 695 479 696 481 697 479 698 479 699 479 700 479 701 480 702 480 703 481 704 479 705 478 706 478 707 476 708 470 709 471 710 474 711 475 712 473 713 475 714 470 715 470 716 468 717 469 718 470 719 468 720 469 721 470 722 469 723 470 724 466 725 466 726 468 727 466 728 467 729 468 730 467 731 462 732 463 733 464 734 466 735 467 736 464 737 466 738 468 739 465 740 465 741 466 742 464 743 465 744 467 745 468 746 466 747 465 748 464 749 464 750 461 751 456 752 460 753 457 754 459 755 458 756 457 757 455 758 453 759 454 760 454 761 454 762 453 763 454 764 452 765 453 766 454 767 456 768 454 769 457 770 458 771 454 772 456 773 454 774 457 775 458 776 457 777 459 778 458 779 457 780 456 781 454 782 453 783 451 784 453 785 455 786 451 787 454 788 452 789 451 790 450 791 450 792 451 793 449 794 444 795 448 796 446 797 444 798 450 799 450 800 448